Interface Engineering of MoS₂/Ni₃S₂Heterostructures for Highly Enhanced Electrochemical Overall-Water-Splitting Activity

To achieve sustainable production of H₂fuel through water splitting, low-cost electrocatalysts for the hydrogen-evolution reaction (HER) and the oxygen-evolution reaction (OER) are required to replace Pt and IrO₂catalysts. Herein, for the first time, we present the interface engineering of novel MoS₂/Ni₃S₂heterostructures, in which abundant interfaces are formed. For OER, such MoS₂/Ni₃S₂heterostructures show an extremely low overpotential of ca. 218 mV at 10 mA cm^-2, which is superior to that of the state-of-the-art OER electrocatalysts. Using MoS₂/Ni₃S₂heterostructures as bifunctional electrocatalysts, an alkali electrolyzer delivers a current density of 10 mA cm^-2at a very low cell voltage of ca. 1.56 V. In combination with DFT calculations, this study demonstrates that the constructed interfaces synergistically favor the chemisorption of hydrogen and oxygen-containing intermediates, thus accelerating the overall electrochemical water splitting.