Interconversion and decomposition of furanones

Zhi Ping Xu; Chup Yew Mok; Wee Shong Chin; Hsing Hua Huang; Sheng Li; Wei Huang

doi:10.1039/a810028d

Interconversion and decomposition of furanones

Zhi Ping Xu
, Chup Yew Mok
, Wee Shong Chin
, Hsing Hua Huang
, Sheng Li
, Wei Huang

National University of Singapore

科研成果: 期刊稿件 › 文章 › 同行评审

9 引用（Scopus）

摘要

The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

源语言	英语
页（从-至）	725-729
页数	5
期刊	Journal of the Chemical Society. Perkin Transactions 2
期	4
DOI	https://doi.org/10.1039/a810028d
出版状态	已出版 - 4月 1999
已对外发布	是

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abstract = "The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.",

author = "Xu, \{Zhi Ping\} and Mok, \{Chup Yew\} and Chin, \{Wee Shong\} and Huang, \{Hsing Hua\} and Sheng Li and Wei Huang",

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AU - Xu, Zhi Ping

AU - Mok, Chup Yew

AU - Chin, Wee Shong

AU - Huang, Hsing Hua

AU - Li, Sheng

AU - Huang, Wei

PY - 1999/4

Y1 - 1999/4

N2 - The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

AB - The interconversion and decomposition of furan-2(3H)- and -2(5H)-one and their methylated derivatives were studied by following the changes in their photoelectron spectra during pyrolysis. Interconversion occurred at 300-400°C and decomposition at around 600°C giving CO and acrolein as the only products for the unsubstituted furanones. The experimental results suggest that decarbonylation takes place through the 2(3H) form as the common precursor.

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DO - 10.1039/a810028d

M3 - 文章

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JO - Journal of the Chemical Society. Perkin Transactions 2

JF - Journal of the Chemical Society. Perkin Transactions 2

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Interconversion and decomposition of furanones

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