In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework

Sara E. Gilson; Peng Li; Jennifer E.S. Szymanowski; Jacob White; Debmalya Ray; Laura Gagliardi; Omar K. Farha; Peter C. Burns

doi:10.1021/jacs.9b06187

In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework

Sara E. Gilson
, Peng Li
, Jennifer E.S. Szymanowski
, Jacob White
, Debmalya Ray
, Laura Gagliardi
, Omar K. Farha
, Peter C. Burns

University of Notre Dame
Northwestern University
University of Minnesota Twin Cities
King Abdulaziz University

科研成果: 期刊稿件 › 文章 › 同行评审

45 引用（Scopus）

摘要

An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-O_yl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.

源语言	英语
页（从-至）	11842-11846
页数	5
期刊	Journal of the American Chemical Society
卷	141
期	30
DOI	https://doi.org/10.1021/jacs.9b06187
出版状态	已出版 - 31 7月 2019
已对外发布	是

访问文件

10.1021/jacs.9b06187

其它文件与链接

链接到 Scopus 的出版物

引用此

@article{e5b1619e6a0a45b19a571a943a8bdeef,

title = "In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework",

abstract = "An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-Oyl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.",

author = "Gilson, \{Sara E.\} and Peng Li and Szymanowski, \{Jennifer E.S.\} and Jacob White and Debmalya Ray and Laura Gagliardi and Farha, \{Omar K.\} and Burns, \{Peter C.\}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = jul,

day = "31",

doi = "10.1021/jacs.9b06187",

language = "英语",

volume = "141",

pages = "11842--11846",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "30",

}

TY - JOUR

T1 - In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework

AU - Gilson, Sara E.

AU - Li, Peng

AU - Szymanowski, Jennifer E.S.

AU - White, Jacob

AU - Ray, Debmalya

AU - Gagliardi, Laura

AU - Farha, Omar K.

AU - Burns, Peter C.

PY - 2019/7/31

Y1 - 2019/7/31

N2 - An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-Oyl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.

AB - An isostructural series of Np(V) MOFs with shp-topology were synthesized and characterized. X-ray diffraction data revealed an unusual wheel-shaped node of 18 neptunyl polyhedra stabilized in the framework. Strong distortion in local coordination of the neptunium atoms is evidenced by Np-Oyl bond lengths that lie outside the typical range for Np(V). The structure was further interrogated by Raman spectroscopy and density functional theory calculations to assign the vibrational modes.

UR - https://www.scopus.com/pages/publications/85070491259

U2 - 10.1021/jacs.9b06187

DO - 10.1021/jacs.9b06187

M3 - 文章

C2 - 31327227

AN - SCOPUS:85070491259

SN - 0002-7863

VL - 141

SP - 11842

EP - 11846

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 30

ER -

In Situ Formation of Unprecedented Neptunium-Oxide Wheel Clusters Stabilized in a Metal-Organic Framework

摘要

访问文件

其它文件与链接

指纹

引用此