Improvement of interfacial compatibility of SiC_f/Ti-6Al-4V composites by applying fiber coating and heat treatment

A new approach to improving the interfacial compatibility of SiC_f/Ti-6Al-4V composites by using fiber coating coupled with subsequent heat treatment was presented. The SiC_f/Ti-6Al-4V composites with C-coated and C/Mo-coated fibers were prepared using the foil-fiber-foil method and subsequently heat treated in vacuum at 750 °C to obtain several kinds of the SiC_f/Ti-6Al-4V composites with different interfacial characteristics. Interfacial microstructures of these composites were systematically characterized by means of scanning electron microscopy and X-ray energy dispersive spectroscopy to investigate the interfacial microstructure evolution and reaction dynamics. The effects of interfacial microstructures on interfacial mechanical properties were also investigated using thin-slice fiber push-out tests. The results show that the brittle interfacial reaction layer of TiC in the C-coated SiC_f/Ti-6Al-4V composites was obviously thickened and some microvoids even formed near the matrix with increasing heat treatment durations, whereas the matrix adjacent to Mo coating in the C/Mo-coated SiC_f/Ti-6Al-4V composites gradually transformed into a ductile β-Ti layer. Interfacial shear strengths of the C/Mo-coated composites were slightly increased with increasing the heat treatment time, while those of the C-coated composites were remarkably improved. Critical issues on modifying interfacial compatibility of the SiC_f/Ti composites for further improving the mechanical behavior of the composites were discussed.