TY - JOUR
T1 - Hydrothermal synthesis, crystal structure and electrochemical behavior of 2D hybrid coordination polymer
AU - Fan, Weiqiang
AU - Zhu, Lin
AU - Shi, Weidong
AU - Chen, Fuxiao
AU - Bai, Hongye
AU - Song, Shuyan
AU - Yan, Yongsheng
PY - 2013/6
Y1 - 2013/6
N2 - A novel metal-organic coordination polymer [Cu(phen)(L) 0.5(H2O)]n (H4L = (N,N′-5,5′-bis(isophthalic acid)-p-xylylenediamine, and phen = 1,10-phenanthroline) has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction. The crystallographic data show that the title compound crystallizes in monoclinic space group P21/n with a = 10.682(2), b = 15.682(3), c = 11.909(2) Å, β = 91.39(3)°, V = 1994.3(7) Å3, C 24H17CuN3O5, Mr = 490.95, Dc = 1.635 g/cm3, F(000) = 1004, Z = 4, μ(MoKα) = 1.141 mm-1, the final R = 0.0418 and wR = 0.0983 for 3578 observed reflections (I > 2σ(I)). The structural analyses reveal that the title compound exhibits shows a 2D layer structure, which are further linked by hydrogen bonding interactions to form a three-dimensional supramolecular network. In addition, the thermal stability and electrochemical behavior of title compound has been studied. CCDC: 900413.
AB - A novel metal-organic coordination polymer [Cu(phen)(L) 0.5(H2O)]n (H4L = (N,N′-5,5′-bis(isophthalic acid)-p-xylylenediamine, and phen = 1,10-phenanthroline) has been hydrothermally synthesized and characterized by elemental analysis, IR, TGA, and single-crystal X-ray diffraction. The crystallographic data show that the title compound crystallizes in monoclinic space group P21/n with a = 10.682(2), b = 15.682(3), c = 11.909(2) Å, β = 91.39(3)°, V = 1994.3(7) Å3, C 24H17CuN3O5, Mr = 490.95, Dc = 1.635 g/cm3, F(000) = 1004, Z = 4, μ(MoKα) = 1.141 mm-1, the final R = 0.0418 and wR = 0.0983 for 3578 observed reflections (I > 2σ(I)). The structural analyses reveal that the title compound exhibits shows a 2D layer structure, which are further linked by hydrogen bonding interactions to form a three-dimensional supramolecular network. In addition, the thermal stability and electrochemical behavior of title compound has been studied. CCDC: 900413.
KW - Hydrothermal synthesis
KW - crystal structure
KW - electrochemical behavior
UR - https://www.scopus.com/pages/publications/84878436496
U2 - 10.1142/S1793604713500276
DO - 10.1142/S1793604713500276
M3 - 文章
AN - SCOPUS:84878436496
SN - 1793-6047
VL - 6
JO - Functional Materials Letters
JF - Functional Materials Letters
IS - 3
M1 - 1350027
ER -