Highly stereoselective synthesis of cyclopropanes based on the ferrocenoyl nitrogen ylide

Ling Shi; Peng Wang; Xueyuan Liu; Weimin Liu; Yongmin Liang

doi:10.1055/s-2004-831176

Highly stereoselective synthesis of cyclopropanes based on the ferrocenoyl nitrogen ylide

Ling Shi
, Peng Wang
, Xueyuan Liu
, Weimin Liu
, Yongmin Liang

Lanzhou University
CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

7 引用（Scopus）

摘要

Ferrocenoyl cyclopropane derivatives were prepared via the reaction of an electron-deficient olefin and a first prepared ferrocenoyl nitrogen ylide. The new compounds 2a-11a have been given in good yields and high stereoselectivity (the ratios of trans to cis diastereoisomers were above 99:1) under the optimum condition and characterized by ¹H NMR, ¹³C NMR, FAB-MS and 1R. The X-ray crystal structure of 8a has also been determined.

源语言	英语
页（从-至）	2342-2346
页数	5
期刊	Synthesis
期	14
DOI	https://doi.org/10.1055/s-2004-831176
出版状态	已出版 - 1 10月 2004
已对外发布	是

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10.1055/s-2004-831176

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title = "Highly stereoselective synthesis of cyclopropanes based on the ferrocenoyl nitrogen ylide",

abstract = "Ferrocenoyl cyclopropane derivatives were prepared via the reaction of an electron-deficient olefin and a first prepared ferrocenoyl nitrogen ylide. The new compounds 2a-11a have been given in good yields and high stereoselectivity (the ratios of trans to cis diastereoisomers were above 99:1) under the optimum condition and characterized by 1H NMR, 13C NMR, FAB-MS and 1R. The X-ray crystal structure of 8a has also been determined.",

keywords = "Cyclopropanation, Electron-deficient, Ferrocenoyl nitrogen ylide, Stereo-selective synthesis, Structure",

author = "Ling Shi and Peng Wang and Xueyuan Liu and Weimin Liu and Yongmin Liang",

year = "2004",

month = oct,

day = "1",

doi = "10.1055/s-2004-831176",

language = "英语",

pages = "2342--2346",

journal = "Synthesis",

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TY - JOUR

T1 - Highly stereoselective synthesis of cyclopropanes based on the ferrocenoyl nitrogen ylide

AU - Shi, Ling

AU - Wang, Peng

AU - Liu, Xueyuan

AU - Liu, Weimin

AU - Liang, Yongmin

PY - 2004/10/1

Y1 - 2004/10/1

N2 - Ferrocenoyl cyclopropane derivatives were prepared via the reaction of an electron-deficient olefin and a first prepared ferrocenoyl nitrogen ylide. The new compounds 2a-11a have been given in good yields and high stereoselectivity (the ratios of trans to cis diastereoisomers were above 99:1) under the optimum condition and characterized by 1H NMR, 13C NMR, FAB-MS and 1R. The X-ray crystal structure of 8a has also been determined.

AB - Ferrocenoyl cyclopropane derivatives were prepared via the reaction of an electron-deficient olefin and a first prepared ferrocenoyl nitrogen ylide. The new compounds 2a-11a have been given in good yields and high stereoselectivity (the ratios of trans to cis diastereoisomers were above 99:1) under the optimum condition and characterized by 1H NMR, 13C NMR, FAB-MS and 1R. The X-ray crystal structure of 8a has also been determined.

KW - Cyclopropanation

KW - Electron-deficient

KW - Ferrocenoyl nitrogen ylide

KW - Stereo-selective synthesis

KW - Structure

UR - https://www.scopus.com/pages/publications/5744229809

U2 - 10.1055/s-2004-831176

DO - 10.1055/s-2004-831176

M3 - 文章

AN - SCOPUS:5744229809

SN - 0039-7881

SP - 2342

EP - 2346

JO - Synthesis

JF - Synthesis

IS - 14

ER -

Highly stereoselective synthesis of cyclopropanes based on the ferrocenoyl nitrogen ylide

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