Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Jingyu Shi; Kangcai Wang; Jing Li; Hongmei Zeng; Qinghua Zhang; Zhien Lin

doi:10.1039/c7dt04125j

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

Jingyu Shi
, Kangcai Wang
, Jing Li
, Hongmei Zeng
, Qinghua Zhang
, Zhien Lin

Sichuan University
China Academy of Engineering Physics

科研成果: 期刊稿件 › 文章 › 同行评审

27 引用（Scopus）

摘要

Two new metal phosphates, namely, Zn(HPO₄)(dl-C₃H₇NO₂) (SCU-4) and In(HPO₄)(H₂PO₄)(dl-C₃H₇NO₂) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

源语言	英语
页（从-至）	654-658
页数	5
期刊	Dalton Transactions
卷	47
期	3
DOI	https://doi.org/10.1039/c7dt04125j
出版状态	已出版 - 2018
已对外发布	是

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abstract = "Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98\% relative humidity.",

author = "Jingyu Shi and Kangcai Wang and Jing Li and Hongmei Zeng and Qinghua Zhang and Zhien Lin",

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T1 - Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

AU - Shi, Jingyu

AU - Wang, Kangcai

AU - Li, Jing

AU - Zeng, Hongmei

AU - Zhang, Qinghua

AU - Lin, Zhien

PY - 2018

Y1 - 2018

N2 - Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

AB - Two new metal phosphates, namely, Zn(HPO4)(dl-C3H7NO2) (SCU-4) and In(HPO4)(H2PO4)(dl-C3H7NO2) (SCU-12), were prepared in the presence of the amino acid l-alanine. SCU-4 has a ladderlike structure with edge-sharing 4-rings. SCU-12 represents the first example of a three-dimensional metal phosphate templated by an amino acid. It remains stable in boiling water and shows a high proton conductivity at room temperature under 98% relative humidity.

UR - https://www.scopus.com/pages/publications/85046105233

U2 - 10.1039/c7dt04125j

DO - 10.1039/c7dt04125j

M3 - 文章

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AN - SCOPUS:85046105233

SN - 1477-9226

VL - 47

SP - 654

EP - 658

JO - Dalton Transactions

JF - Dalton Transactions

IS - 3

ER -

Exploration of new water stable proton-conducting materials in an amino acid-templated metal phosphate system

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