Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

Shu Guang Wen; Wei Min Liu; Yong Min Liang

doi:10.1021/jo800556e

Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

Shu Guang Wen
, Wei Min Liu
, Yong Min Liang

CAS - Lanzhou Institute of Chemical Physics
University of Chinese Academy of Sciences
Lanzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

24 引用（Scopus）

摘要

(Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

源语言	英语
页（从-至）	4342-4344
页数	3
期刊	Journal of Organic Chemistry
卷	73
期	11
DOI	https://doi.org/10.1021/jo800556e
出版状态	已出版 - 6 6月 2008
已对外发布	是

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10.1021/jo800556e

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abstract = "(Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.",

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N2 - (Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

AB - (Chemical Equation Presented) A novel method for the construction of 2,3-dihydro-5-iodopyran-4-one through a domino cyclization/migration reaction of 1-alkynyl-2,3-epoxy alcohol was developed. Wet solvent is essential for this reaction. The resulting iodine-containing product can be readily elaborated to more complex products by using known organopalladium chemistry.

UR - https://www.scopus.com/pages/publications/44949255440

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DO - 10.1021/jo800556e

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Electrophile-induced cyclization/migration reaction for the synthesis of 2,3-dihydro-5-iodopyran-4-one

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