TY - JOUR
T1 - Effect of E-44 Epoxy Resin and Pyrolysis Temperature on the Adhesion Strength of SiBCN Ceramic
AU - Ma, Zhibo
AU - Chang, Sen
AU - Song, Xuemei
AU - Li, Min
AU - Wang, Kunjun
AU - Li, Yongguo
AU - Xu, Xinming
AU - Zhang, Qiqi
AU - Wang, Lei
AU - Yu, Rong
AU - Luan, Xin’gang
AU - Cheng, Laifei
N1 - Publisher Copyright:
© 2020, Wuhan University of Technology and Springer-Verlag GmbH Germany, Part of Springer Nature.
PY - 2020/2/1
Y1 - 2020/2/1
N2 - An adhesive of the SiBCN ceramic was synthesized through the polymer derived ceramics (PDC) route. Meanwhile with higher adhesion strength and simpler process condition, the polyborosilazane (PSNB) was modified by E-44 epoxy resin. The E-44 epoxy resin was used to promote the oxidation process of SiBCN, in other words, to produce more amount of SiO2-B2O3 glasses. The phase composition, elemental analysis, chemical bonds and microstructure were investigated by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) measurements. The E-44 modified adhesives were cured at 120 °C in air for 2 h, and were pyrolyzed at 1 200, 1 400, and 1 500 °C for 2 h in air, respectively. The highest adhesion strength of the modified adhesive was up to 5.33, 12.23, and 12.50 MPa after being heat treated at 1 200, 1 400, and 1 500 °C, respectively. Finally, we proposed an adhesion model and revealed the adhesion mechanism of SiBCN ceramic.
AB - An adhesive of the SiBCN ceramic was synthesized through the polymer derived ceramics (PDC) route. Meanwhile with higher adhesion strength and simpler process condition, the polyborosilazane (PSNB) was modified by E-44 epoxy resin. The E-44 epoxy resin was used to promote the oxidation process of SiBCN, in other words, to produce more amount of SiO2-B2O3 glasses. The phase composition, elemental analysis, chemical bonds and microstructure were investigated by using X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and scanning electron microscope (SEM) measurements. The E-44 modified adhesives were cured at 120 °C in air for 2 h, and were pyrolyzed at 1 200, 1 400, and 1 500 °C for 2 h in air, respectively. The highest adhesion strength of the modified adhesive was up to 5.33, 12.23, and 12.50 MPa after being heat treated at 1 200, 1 400, and 1 500 °C, respectively. Finally, we proposed an adhesion model and revealed the adhesion mechanism of SiBCN ceramic.
KW - E-44 epoxy resin
KW - PDC route
KW - pyrolysis temperature
KW - SiBCN ceramic
KW - SiO-BO glasses
UR - https://www.scopus.com/pages/publications/85083179036
U2 - 10.1007/s11595-020-2230-8
DO - 10.1007/s11595-020-2230-8
M3 - 文章
AN - SCOPUS:85083179036
SN - 1000-2413
VL - 35
SP - 81
EP - 86
JO - Journal Wuhan University of Technology, Materials Science Edition
JF - Journal Wuhan University of Technology, Materials Science Edition
IS - 1
ER -