Broadening through-space conjugation in polyphosphates through α-aminophosphonate bridges for a noteworthy red shift in luminescence

Zheng Li; Pengfei Yang; Rui Wu; Qingyuan Meng; Jinyi Liu; Yan Zhao; Hongxia Yan

doi:10.1039/d5cc07165h

Broadening through-space conjugation in polyphosphates through α-aminophosphonate bridges for a noteworthy red shift in luminescence

Zheng Li
, Pengfei Yang
, Rui Wu
, Qingyuan Meng
, Jinyi Liu
, Yan Zhao
, Hongxia Yan

化学与化工学院

Northwestern Polytechnical University Xian

科研成果: 期刊稿件 › 文章 › 同行评审

摘要

Incorporating α-aminophosphonate bridges into polyphosphonate chains effectively broadens the through-space conjugation (TSC), enhancing spatial electron delocalization. This results in a notable emission redshift to 630 nm with remarkable efficiency, demonstrating a robust structure–property relationship in the unconventional fluorescent polymers.

源语言	英语
页（从-至）	5019-5022
页数	4
期刊	Chemical Communications
卷	62
期	17
DOI	https://doi.org/10.1039/d5cc07165h
出版状态	已出版 - 3 3月 2026

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10.1039/d5cc07165h

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abstract = "Incorporating α-aminophosphonate bridges into polyphosphonate chains effectively broadens the through-space conjugation (TSC), enhancing spatial electron delocalization. This results in a notable emission redshift to 630 nm with remarkable efficiency, demonstrating a robust structure{\textendash}property relationship in the unconventional fluorescent polymers.",

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AU - Li, Zheng

AU - Yang, Pengfei

AU - Wu, Rui

AU - Meng, Qingyuan

AU - Liu, Jinyi

AU - Zhao, Yan

AU - Yan, Hongxia

PY - 2026/3/3

Y1 - 2026/3/3

N2 - Incorporating α-aminophosphonate bridges into polyphosphonate chains effectively broadens the through-space conjugation (TSC), enhancing spatial electron delocalization. This results in a notable emission redshift to 630 nm with remarkable efficiency, demonstrating a robust structure–property relationship in the unconventional fluorescent polymers.

AB - Incorporating α-aminophosphonate bridges into polyphosphonate chains effectively broadens the through-space conjugation (TSC), enhancing spatial electron delocalization. This results in a notable emission redshift to 630 nm with remarkable efficiency, demonstrating a robust structure–property relationship in the unconventional fluorescent polymers.

UR - https://www.scopus.com/pages/publications/105030468012

U2 - 10.1039/d5cc07165h

DO - 10.1039/d5cc07165h

M3 - 文章

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AN - SCOPUS:105030468012

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JO - Chemical Communications

JF - Chemical Communications

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Broadening through-space conjugation in polyphosphates through α-aminophosphonate bridges for a noteworthy red shift in luminescence

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