Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

Mingjin Fan; Lin Ma; Chaoyang Zhang; Zijing Wang; Jiacheng Ruan; Mei Han; Yuyu Ren; Chi Zhang; Desuo Yang; Feng Zhou; Weimin Liu

doi:10.1080/10402004.2017.1290856

Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

Mingjin Fan
, Lin Ma
, Chaoyang Zhang
, Zijing Wang
, Jiacheng Ruan
, Mei Han
, Yuyu Ren
, Chi Zhang
, Desuo Yang
, Feng Zhou
, Weimin Liu

Baoji University of Arts and Sciences
Baoji Middle School
CAS - Lanzhou Institute of Chemical Physics

科研成果: 期刊稿件 › 文章 › 同行评审

39 引用（Scopus）

摘要

Fatty acid ionic liquids (FAILs) were designed and synthesized by combining quaternary ammonium cations with a range of biobased fatty acid anions. They were found to be good and universal lubricants for steel–steel, steel–copper, and steel–aluminum friction pairs, which possess low corrosivities, moderate viscosity indexes, and thermal stabilities compared to commercially available synthetic oil polyalphaolefin (PAO) 10 and traditional ionic liquid (IL) L-F104. Among them, N₁₄₄₄Oct and N₄₄₄₄Oct were found to have far lower toxicity than L-F104. Investigation of the lubricating mechanism revealed that firm and effective physical adsorption and tribochemical reaction films can be easily formed on the sliding surface due to the polarity of the fatty acid anions and the aliphatic tails, which prevent metal–metal contact and further antiwear and reduce friction.

源语言	英语
页（从-至）	195-206
页数	12
期刊	Tribology Transactions
卷	61
期	2
DOI	https://doi.org/10.1080/10402004.2017.1290856
出版状态	已出版 - 4 3月 2018
已对外发布	是

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title = "Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids",

abstract = "Fatty acid ionic liquids (FAILs) were designed and synthesized by combining quaternary ammonium cations with a range of biobased fatty acid anions. They were found to be good and universal lubricants for steel–steel, steel–copper, and steel–aluminum friction pairs, which possess low corrosivities, moderate viscosity indexes, and thermal stabilities compared to commercially available synthetic oil polyalphaolefin (PAO) 10 and traditional ionic liquid (IL) L-F104. Among them, N1444Oct and N4444Oct were found to have far lower toxicity than L-F104. Investigation of the lubricating mechanism revealed that firm and effective physical adsorption and tribochemical reaction films can be easily formed on the sliding surface due to the polarity of the fatty acid anions and the aliphatic tails, which prevent metal–metal contact and further antiwear and reduce friction.",

keywords = "Fatty acid, ionic liquid, lubricant, quaternary ammonium, toxicity",

author = "Mingjin Fan and Lin Ma and Chaoyang Zhang and Zijing Wang and Jiacheng Ruan and Mei Han and Yuyu Ren and Chi Zhang and Desuo Yang and Feng Zhou and Weimin Liu",

note = "Publisher Copyright: {\textcopyright} 2018 Society of Tribologists and Lubrication Engineers.",

year = "2018",

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doi = "10.1080/10402004.2017.1290856",

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T1 - Biobased Green Lubricants

T2 - Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

AU - Fan, Mingjin

AU - Ma, Lin

AU - Zhang, Chaoyang

AU - Wang, Zijing

AU - Ruan, Jiacheng

AU - Han, Mei

AU - Ren, Yuyu

AU - Zhang, Chi

AU - Yang, Desuo

AU - Zhou, Feng

AU - Liu, Weimin

PY - 2018/3/4

Y1 - 2018/3/4

N2 - Fatty acid ionic liquids (FAILs) were designed and synthesized by combining quaternary ammonium cations with a range of biobased fatty acid anions. They were found to be good and universal lubricants for steel–steel, steel–copper, and steel–aluminum friction pairs, which possess low corrosivities, moderate viscosity indexes, and thermal stabilities compared to commercially available synthetic oil polyalphaolefin (PAO) 10 and traditional ionic liquid (IL) L-F104. Among them, N1444Oct and N4444Oct were found to have far lower toxicity than L-F104. Investigation of the lubricating mechanism revealed that firm and effective physical adsorption and tribochemical reaction films can be easily formed on the sliding surface due to the polarity of the fatty acid anions and the aliphatic tails, which prevent metal–metal contact and further antiwear and reduce friction.

AB - Fatty acid ionic liquids (FAILs) were designed and synthesized by combining quaternary ammonium cations with a range of biobased fatty acid anions. They were found to be good and universal lubricants for steel–steel, steel–copper, and steel–aluminum friction pairs, which possess low corrosivities, moderate viscosity indexes, and thermal stabilities compared to commercially available synthetic oil polyalphaolefin (PAO) 10 and traditional ionic liquid (IL) L-F104. Among them, N1444Oct and N4444Oct were found to have far lower toxicity than L-F104. Investigation of the lubricating mechanism revealed that firm and effective physical adsorption and tribochemical reaction films can be easily formed on the sliding surface due to the polarity of the fatty acid anions and the aliphatic tails, which prevent metal–metal contact and further antiwear and reduce friction.

KW - Fatty acid

KW - ionic liquid

KW - lubricant

KW - quaternary ammonium

KW - toxicity

UR - https://www.scopus.com/pages/publications/85015145695

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DO - 10.1080/10402004.2017.1290856

M3 - 文章

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SN - 1040-2004

VL - 61

SP - 195

EP - 206

JO - Tribology Transactions

JF - Tribology Transactions

IS - 2

ER -

Biobased Green Lubricants: Physicochemical, Tribological and Toxicological Properties of Fatty Acid Ionic Liquids

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