Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

Biao Zhang; Xibo Yan; Pierre Alcouffe; Aurelia Charlot; Etienne Fleury; Julien Bernard

doi:10.1021/acsmacrolett.5b00534

Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

Biao Zhang
, Xibo Yan
, Pierre Alcouffe
, Aurelia Charlot
, Etienne Fleury
, Julien Bernard

Université de Lyon
Institut national des sciences appliquées Lyon
CNRS

科研成果: 期刊稿件 › 快报 › 同行评审

61 引用（Scopus）

摘要

The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

源语言	英语
页（从-至）	1008-1011
页数	4
期刊	ACS Macro Letters
卷	4
期	9
DOI	https://doi.org/10.1021/acsmacrolett.5b00534
出版状态	已出版 - 15 9月 2015
已对外发布	是

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title = "Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly",

abstract = "The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s ({\D} typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.",

author = "Biao Zhang and Xibo Yan and Pierre Alcouffe and Aurelia Charlot and Etienne Fleury and Julien Bernard",

note = "Publisher Copyright: Copyright {\textcopyright} 2015 American Chemical Society",

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doi = "10.1021/acsmacrolett.5b00534",

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T1 - Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers

T2 - En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

AU - Zhang, Biao

AU - Yan, Xibo

AU - Alcouffe, Pierre

AU - Charlot, Aurelia

AU - Fleury, Etienne

AU - Bernard, Julien

PY - 2015/9/15

Y1 - 2015/9/15

N2 - The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

AB - The synthesis by aqueous RAFT polymerization of hydrophilic narrowly dispersed imidazolium-based poly(ionic liquid)s (Đ typically below 1.20) is reported. Full monomer conversion is achieved within hours and high end-group fidelity of the living end groups affords the preparation of well-defined block copolymers. The resulting poly(ionic liquid) macroRAFT agents are finally exploited to polymerize 2-vinylpyridine in water and generate PIL-based nanoparticles of various morphologies (spheres, vesicles, or worms) in a one-pot surfactant-free process.

UR - https://www.scopus.com/pages/publications/84941646784

U2 - 10.1021/acsmacrolett.5b00534

DO - 10.1021/acsmacrolett.5b00534

M3 - 快报

AN - SCOPUS:84941646784

SN - 2161-1653

VL - 4

SP - 1008

EP - 1011

JO - ACS Macro Letters

JF - ACS Macro Letters

IS - 9

ER -

Aqueous RAFT Polymerization of Imidazolium-Type Ionic Liquid Monomers: En Route to Poly(ionic liquid)-Based Nanoparticles through RAFT Polymerization-Induced Self-Assembly

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