TY - JOUR
T1 - A rare cationic building block that generates a new type of polyhedral network with "cross-linked" pto topology
AU - Lusi, Matteo
AU - Fechine, Pierre B.A.
AU - Chen, Kai Jie
AU - Perry, John J.
AU - Zaworotko, Michael J.
N1 - Publisher Copyright:
© The Royal Society of Chemistry 2016.
PY - 2016
Y1 - 2016
N2 - A rare 8-connected cationic building block, [Cu2L8(μ-MF6)]2+ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF62- moieties, and represents the first example of a new 3,5-c topology.
AB - A rare 8-connected cationic building block, [Cu2L8(μ-MF6)]2+ (L = pyridyl ligand, M = Si, Ti, Ge, Zr or Sn), enables the formation of a small cubicuboctahedral supramolecular building block, SBB, when complexed by 2,4,6-tris(4-pyridyl)pyridine. The coordination network resulting from fusing the square faces of the SBBs can be described as a pto topology in which half of the square faces are cross-linked by MF62- moieties, and represents the first example of a new 3,5-c topology.
UR - http://www.scopus.com/inward/record.url?scp=84960405712&partnerID=8YFLogxK
U2 - 10.1039/c5cc10203k
DO - 10.1039/c5cc10203k
M3 - 文章
AN - SCOPUS:84960405712
SN - 1359-7345
VL - 52
SP - 4160
EP - 4162
JO - Chemical Communications
JF - Chemical Communications
IS - 22
ER -