A new zeolitic lithium aluminum imidazolate framework

Guangshen Jiang; Volodymyr Bon; Fei Xu; Bikash Garai; En Zhang; Irena Senkovska; Stephanie Poetke; Felix Hippauf; Steffen Hausdorf; Silvia Paasch; Eike Brunner; Hongqiang Wang; Stefan Kaskel

doi:10.1039/d1dt01017d

A new zeolitic lithium aluminum imidazolate framework

Guangshen Jiang
, Volodymyr Bon
, Fei Xu
, Bikash Garai
, En Zhang
, Irena Senkovska
, Stephanie Poetke
, Felix Hippauf
, Steffen Hausdorf
, Silvia Paasch
, Eike Brunner
, Hongqiang Wang
, Stefan Kaskel

材料学院

Northwestern Polytechnical University Xian
Technische Universität Dresden
Fraunhofer Institute for Material and Beam Technology

科研成果: 期刊稿件 › 文章 › 同行评审

4 引用（Scopus）

摘要

An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)₄]_n, isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH₄) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)^-. DUT-174 has a high specific surface area of 1149 m²g⁻¹and CO₂uptake of 11.57 mmol g⁻¹at 195 K.

源语言	英语
页（从-至）	7933-7937
页数	5
期刊	Dalton Transactions
卷	50
期	23
DOI	https://doi.org/10.1039/d1dt01017d
出版状态	已出版 - 21 6月 2021

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10.1039/d1dt01017d

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title = "A new zeolitic lithium aluminum imidazolate framework",

abstract = "An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)4]n, isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH4) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)-. DUT-174 has a high specific surface area of 1149 m2g−1and CO2uptake of 11.57 mmol g−1at 195 K.",

author = "Guangshen Jiang and Volodymyr Bon and Fei Xu and Bikash Garai and En Zhang and Irena Senkovska and Stephanie Poetke and Felix Hippauf and Steffen Hausdorf and Silvia Paasch and Eike Brunner and Hongqiang Wang and Stefan Kaskel",

note = "Publisher Copyright: {\textcopyright} The Royal Society of Chemistry 2021.",

year = "2021",

month = jun,

day = "21",

doi = "10.1039/d1dt01017d",

language = "英语",

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TY - JOUR

T1 - A new zeolitic lithium aluminum imidazolate framework

AU - Jiang, Guangshen

AU - Bon, Volodymyr

AU - Xu, Fei

AU - Garai, Bikash

AU - Zhang, En

AU - Senkovska, Irena

AU - Poetke, Stephanie

AU - Hippauf, Felix

AU - Hausdorf, Steffen

AU - Paasch, Silvia

AU - Brunner, Eike

AU - Wang, Hongqiang

AU - Kaskel, Stefan

PY - 2021/6/21

Y1 - 2021/6/21

N2 - An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)4]n, isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH4) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)-. DUT-174 has a high specific surface area of 1149 m2g−1and CO2uptake of 11.57 mmol g−1at 195 K.

AB - An aliovalent mixed-metal framework DUT-174 [LiAl(2-methylimidazolate)4]n, isostructural to ZIF-8, was synthesized from lithium aluminum hydride (LiAlH4) and 2-methylimidazole (2-mImH) through dehydrogenation. Lithium and aluminum cations acting as alternating framework nodes are coordinated tetrahedrally by (2-mIm)-. DUT-174 has a high specific surface area of 1149 m2g−1and CO2uptake of 11.57 mmol g−1at 195 K.

UR - https://www.scopus.com/pages/publications/85107903636

U2 - 10.1039/d1dt01017d

DO - 10.1039/d1dt01017d

M3 - 文章

C2 - 34075989

AN - SCOPUS:85107903636

SN - 1477-9226

VL - 50

SP - 7933

EP - 7937

JO - Dalton Transactions

JF - Dalton Transactions

IS - 23

ER -

A new zeolitic lithium aluminum imidazolate framework

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