A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands

Zhi Bing Dong; Bing Liu; Cao Fang; Jin Shan Li

doi:10.1016/j.jorganchem.2007.10.008

A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands

Zhi Bing Dong
, Bing Liu
, Cao Fang
, Jin Shan Li

Nankai University

科研成果: 期刊稿件 › 文章 › 同行评审

10 引用（Scopus）

摘要

Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93% ee and 97% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.

源语言	英语
页（从-至）	17-22
页数	6
期刊	Journal of Organometallic Chemistry
卷	693
期	1
DOI	https://doi.org/10.1016/j.jorganchem.2007.10.008
出版状态	已出版 - 1 1月 2008
已对外发布	是

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title = "A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands",

abstract = "Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93\% ee and 97\% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.",

keywords = "Asymmetric addition, BINOL, Copper trifluoromethanesulfonate, Diethylzinc, Titanium tetraisopropoxide",

author = "Dong, \{Zhi Bing\} and Bing Liu and Cao Fang and Li, \{Jin Shan\}",

year = "2008",

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doi = "10.1016/j.jorganchem.2007.10.008",

language = "英语",

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TY - JOUR

T1 - A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands

AU - Dong, Zhi Bing

AU - Liu, Bing

AU - Fang, Cao

AU - Li, Jin Shan

PY - 2008/1/1

Y1 - 2008/1/1

N2 - Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93% ee and 97% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.

AB - Four new BINOL-based thiazole (thiadiazole) thioether ligands (S)-1, (S)-2, (S,S)-3 and (S)-4 were prepared. When their catalytic effectiveness was tested, good results (up to 93% ee and 97% yield) were obtained in the asymmetric addition of diethylzinc to aldehydes while poor results were obtained in the asymmetric conjugate addition of diethylzinc to enones.

KW - Asymmetric addition

KW - BINOL

KW - Copper trifluoromethanesulfonate

KW - Diethylzinc

KW - Titanium tetraisopropoxide

UR - https://www.scopus.com/pages/publications/36749043709

U2 - 10.1016/j.jorganchem.2007.10.008

DO - 10.1016/j.jorganchem.2007.10.008

M3 - 文章

AN - SCOPUS:36749043709

SN - 0022-328X

VL - 693

SP - 17

EP - 22

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 1

ER -

A facile synthesis and the asymmetric catalytic activity of BINOL-based thiazole (thiadiazole) thioether ligands

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