A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions

Yun Hu Han; Zhong Yuan Zhou; Chong Bin Tian; Shao Wu Du

doi:10.1039/c6gc00413j

A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO₂ under mild and co-catalyst free conditions

Yun Hu Han
, Zhong Yuan Zhou
, Chong Bin Tian
, Shao Wu Du

CAS - Fujian Institute of Research on the Structure of Matter
University of Chinese Academy of Sciences
Fuzhou University

科研成果: 期刊稿件 › 文章 › 同行评审

132 引用（Scopus）

摘要

A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn₆(TATAB)₄(DABCO)₃(H₂O)₃]·12DMF·9H₂O (1) (H₃TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO₂ of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO₂ into propylene carbonate under mild conditions (100 °C and ambient CO₂ pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

源语言	英语
页（从-至）	4086-4091
页数	6
期刊	Green Chemistry
卷	18
期	14
DOI	https://doi.org/10.1039/c6gc00413j
出版状态	已出版 - 2016
已对外发布	是

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10.1039/c6gc00413j

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@article{abdcda3678dc4551ab76aa82c797b363,

title = "A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions",

abstract = "A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99\% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.",

author = "Han, \{Yun Hu\} and Zhou, \{Zhong Yuan\} and Tian, \{Chong Bin\} and Du, \{Shao Wu\}",

note = "Publisher Copyright: {\textcopyright} 2016 The Royal Society of Chemistry.",

year = "2016",

doi = "10.1039/c6gc00413j",

language = "英语",

volume = "18",

pages = "4086--4091",

journal = "Green Chemistry",

issn = "1463-9262",

publisher = "Royal Society of Chemistry",

number = "14",

}

TY - JOUR

T1 - A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions

AU - Han, Yun Hu

AU - Zhou, Zhong Yuan

AU - Tian, Chong Bin

AU - Du, Shao Wu

PY - 2016

Y1 - 2016

N2 - A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

AB - A novel 3D → 3D interpenetrated Zn-polyhedral MOF [Zn6(TATAB)4(DABCO)3(H2O)3]·12DMF·9H2O (1) (H3TATAB = 4,4′,4′′-s-triazine-1,3,5-triyl-tri-p-aminobenzoic acid, DABCO = 1,4-diazabicyclo[2.2.2]octane) based on a dual-walled icosahedral cage has been assembled by incorporating zinc paddlewheel units with nitrogen-rich tritopic carboxylate ligands. Owing to the high density of Lewis acid active sites and affinity to CO2 of the cage, this material exhibits an excellent catalytic efficiency in the cycloaddition of propylene oxide with CO2 into propylene carbonate under mild conditions (100 °C and ambient CO2 pressure) with a high yield of 99% over 16 h. Moreover, the catalytic reaction is environmentally friendly without any need for co-catalysts and solvents.

UR - https://www.scopus.com/pages/publications/84978898818

U2 - 10.1039/c6gc00413j

DO - 10.1039/c6gc00413j

M3 - 文章

AN - SCOPUS:84978898818

SN - 1463-9262

VL - 18

SP - 4086

EP - 4091

JO - Green Chemistry

JF - Green Chemistry

IS - 14

ER -

A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO2 under mild and co-catalyst free conditions

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A dual-walled cage MOF as an efficient heterogeneous catalyst for the conversion of CO₂ under mild and co-catalyst free conditions