3-Substituted BINOL schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes

Bing Liu; Zhi Bing Dong; Cao Fang; Hai Bin Song; Jin Shan Li

doi:10.1002/chir.20559

3-Substituted BINOL schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes

Bing Liu
, Zhi Bing Dong
, Cao Fang
, Hai Bin Song
, Jin Shan Li

Nankai University
Tianjin University of Science & Technology

科研成果: 期刊稿件 › 文章 › 同行评审

8 引用（Scopus）

摘要

Three new chiral 3-substituted BINOL Schiff bases and their reductive 3-arylaminomethylBINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active secondary alcohols in high yield (86-100%) and good enantioselectivity (up to 92% ee).

源语言	英语
页（从-至）	828-832
页数	5
期刊	Chirality
卷	20
期	7
DOI	https://doi.org/10.1002/chir.20559
出版状态	已出版 - 7月 2008
已对外发布	是

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title = "3-Substituted BINOL schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes",

abstract = "Three new chiral 3-substituted BINOL Schiff bases and their reductive 3-arylaminomethylBINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active secondary alcohols in high yield (86-100\%) and good enantioselectivity (up to 92\% ee).",

keywords = "Aldehyde, Asymmetric addition, BINOL, Schiff base, Titanium",

author = "Bing Liu and Dong, \{Zhi Bing\} and Cao Fang and Song, \{Hai Bin\} and Li, \{Jin Shan\}",

year = "2008",

month = jul,

doi = "10.1002/chir.20559",

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T1 - 3-Substituted BINOL schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes

AU - Liu, Bing

AU - Dong, Zhi Bing

AU - Fang, Cao

AU - Song, Hai Bin

AU - Li, Jin Shan

PY - 2008/7

Y1 - 2008/7

N2 - Three new chiral 3-substituted BINOL Schiff bases and their reductive 3-arylaminomethylBINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active secondary alcohols in high yield (86-100%) and good enantioselectivity (up to 92% ee).

AB - Three new chiral 3-substituted BINOL Schiff bases and their reductive 3-arylaminomethylBINOL products have been synthesized and used for the asymmetric addition reaction of diethylzinc to aldehydes in the presence of titanium tetraisopropoxide. The reaction provided optically active secondary alcohols in high yield (86-100%) and good enantioselectivity (up to 92% ee).

KW - Aldehyde

KW - Asymmetric addition

KW - BINOL

KW - Schiff base

KW - Titanium

UR - https://www.scopus.com/pages/publications/45849142569

U2 - 10.1002/chir.20559

DO - 10.1002/chir.20559

M3 - 文章

C2 - 18338388

AN - SCOPUS:45849142569

SN - 0899-0042

VL - 20

SP - 828

EP - 832

JO - Chirality

JF - Chirality

IS - 7

ER -

3-Substituted BINOL schiff bases and their reductive products for catalytic asymmetric addition of diethylzinc to aldehydes

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