1,2,3-Triazolium-based poly(acrylate ionic liquid)s

Rakhi Sood; Mona Marie Obadia; Bhanu Prakash Mudraboyina; Biao Zhang; Anatoli Serghei; Julien Bernard; Eric Drockenmuller

doi:10.1016/j.polymer.2014.04.017

1,2,3-Triazolium-based poly(acrylate ionic liquid)s

Rakhi Sood
, Mona Marie Obadia
, Bhanu Prakash Mudraboyina
, Biao Zhang
, Anatoli Serghei
, Julien Bernard
, Eric Drockenmuller

INSA Lyon
Institut universitaire de France

科研成果: 期刊稿件 › 文章 › 同行评审

41 引用（Scopus）

摘要

Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (M_n = 7860 g mol^-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (T_g = -40 °C), high thermal stability (T_d10 = 325 °C) and anhydrous ionic conductivity of 4 × 10^-6 S cm^-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

源语言	英语
页（从-至）	3314-3319
页数	6
期刊	Polymer
卷	55
期	16
DOI	https://doi.org/10.1016/j.polymer.2014.04.017
出版状态	已出版 - 5 8月 2014
已对外发布	是

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title = "1,2,3-Triazolium-based poly(acrylate ionic liquid)s",

abstract = "Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.",

keywords = "Click chemistry, Nitroxide-mediated radical polymerization, Poly(ionic liquid)s",

author = "Rakhi Sood and Obadia, \{Mona Marie\} and Mudraboyina, \{Bhanu Prakash\} and Biao Zhang and Anatoli Serghei and Julien Bernard and Eric Drockenmuller",

year = "2014",

month = aug,

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doi = "10.1016/j.polymer.2014.04.017",

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T1 - 1,2,3-Triazolium-based poly(acrylate ionic liquid)s

AU - Sood, Rakhi

AU - Obadia, Mona Marie

AU - Mudraboyina, Bhanu Prakash

AU - Zhang, Biao

AU - Serghei, Anatoli

AU - Bernard, Julien

AU - Drockenmuller, Eric

PY - 2014/8/5

Y1 - 2014/8/5

N2 - Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

AB - Nitroxide-mediated radical polymerization of a tailor-made acrylate carrying a 1,2,3-triazole group with an undecanoyl spacer affords a well-defined (Mn = 7860 g mol-1 and D = 1.39) neutral polyacrylate precursor. A series of 1,2,3-triazolium-based poly(ionic liquid)s (TPILs) is then obtained by straightforward quaternization of the 1,2,3-triazole groups with methyl iodide and subsequent anion metathesis reactions. Among the prepared materials, TPIL with bis(trifluoromethane)sulfonimide anion exhibits low glass transition temperature (Tg = -40 °C), high thermal stability (Td10 = 325 °C) and anhydrous ionic conductivity of 4 × 10-6 S cm-1 at 30 °C, as measured by differential scanning calorimetry, thermogravimetric analysis and broadband dielectric spectroscopy, respectively.

KW - Click chemistry

KW - Nitroxide-mediated radical polymerization

KW - Poly(ionic liquid)s

UR - https://www.scopus.com/pages/publications/84905485722

U2 - 10.1016/j.polymer.2014.04.017

DO - 10.1016/j.polymer.2014.04.017

M3 - 文章

AN - SCOPUS:84905485722

SN - 0032-3861

VL - 55

SP - 3314

EP - 3319

JO - Polymer

JF - Polymer

IS - 16

ER -

1,2,3-Triazolium-based poly(acrylate ionic liquid)s

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