Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi; Huibin Sun; Xiao Tang; Wen Lv; Hong Yan; Qiang Zhao; Jingxia Wang; Wei Huang

doi:10.1002/anie.201307333

Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

Chao Shi
, Huibin Sun
, Xiao Tang
, Wen Lv
, Hong Yan
, Qiang Zhao
, Jingxia Wang
, Wei Huang

Nanjing University
Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

202 Scopus citations

Abstract

Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

Original language	English
Pages (from-to)	13434-13438
Number of pages	5
Journal	Angewandte Chemie - International Edition
Volume	52
Issue number	50
DOIs	https://doi.org/10.1002/anie.201307333
State	Published - 9 Dec 2013
Externally published	Yes

Keywords

bioimaging
carboranes
iridium
phosphorescence

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10.1002/anie.201307333

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title = "Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution",

abstract = "Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.",

keywords = "bioimaging, carboranes, iridium, phosphorescence",

author = "Chao Shi and Huibin Sun and Xiao Tang and Wen Lv and Hong Yan and Qiang Zhao and Jingxia Wang and Wei Huang",

year = "2013",

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doi = "10.1002/anie.201307333",

language = "英语",

volume = "52",

pages = "13434--13438",

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T1 - Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

AU - Shi, Chao

AU - Sun, Huibin

AU - Tang, Xiao

AU - Lv, Wen

AU - Yan, Hong

AU - Zhao, Qiang

AU - Wang, Jingxia

AU - Huang, Wei

PY - 2013/12/9

Y1 - 2013/12/9

N2 - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

AB - Phosphorescent iridium(III) complexes with three bidentate carborane-functionalized ligands have been synthesized. The luminescent efficiency of the o-carborane-based facial complex fac-o shows solvent-molecule dependence both in solution and solid state that is related to the dielectric constant. The water-soluble and high phosphorescence-efficient nido complex nido-fac-o can be used in fluorescence lifetime bioimaging.

KW - bioimaging

KW - carboranes

KW - iridium

KW - phosphorescence

UR - https://www.scopus.com/pages/publications/84889684547

U2 - 10.1002/anie.201307333

DO - 10.1002/anie.201307333

M3 - 文章

AN - SCOPUS:84889684547

SN - 1433-7851

VL - 52

SP - 13434

EP - 13438

JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 50

ER -

Variable photophysical properties of phosphorescent iridium(III) complexes triggered by closo- and nido-carborane substitution

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Keywords

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