Unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units for the construction of a metal-organic framework

Hui Yang; Tie Hu Li; Yao Kang; Fei Wang

doi:10.1016/j.inoche.2012.09.012

Unusual Zn ₅(μ ₃-OH) ₂(COO ^-) ₈ secondary building units for the construction of a metal-organic framework

Hui Yang
, Tie Hu Li
, Yao Kang
, Fei Wang

School of Materials Sience and Engineering

Northwestern Polytechnical University Xian
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

A new three-dimensional (3D) metal-organic framework (MOF) {Zn ₅(μ ₃-OH) ₂(obb) ₄[(CH ₃) ₂NH] ₂}·2DMF (1; H ₂obb = 4,4′-oxybisbenzoic acid; DMF = N,N′-dimethyl formamide) with unusual Zn ₅(μ ₃-OH) ₂(COO ^-) ₈ secondary building units (SBUs) has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Elemental analysis (EA) and Infrared Spectroscopy (IR). The unprecedented pentanuclear Zn ₅(μ ₃-OH) ₂(COO ^-) ₈ SBU was formed by two trimeric Zn ₃(μ ₃-OH)(COO ^-) ₆ SBUs, which can be simplified as 4-connected node. Correspondingly, compound 1 exhibits dia structural topology.

Original language	English
Pages (from-to)	92-95
Number of pages	4
Journal	Inorganic Chemistry Communications
Volume	25
DOIs	https://doi.org/10.1016/j.inoche.2012.09.012
State	Published - Nov 2012

Keywords

Crystal structure
Metal-organic framework
SBUs
Topology
Zinc

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10.1016/j.inoche.2012.09.012

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@article{a59f94c35f504a28998f0161a71034c7,

title = "Unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units for the construction of a metal-organic framework",

abstract = "A new three-dimensional (3D) metal-organic framework (MOF) \{Zn 5(μ 3-OH) 2(obb) 4[(CH 3) 2NH] 2\}·2DMF (1; H 2obb = 4,4′-oxybisbenzoic acid; DMF = N,N′-dimethyl formamide) with unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units (SBUs) has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Elemental analysis (EA) and Infrared Spectroscopy (IR). The unprecedented pentanuclear Zn 5(μ 3-OH) 2(COO -) 8 SBU was formed by two trimeric Zn 3(μ 3-OH)(COO -) 6 SBUs, which can be simplified as 4-connected node. Correspondingly, compound 1 exhibits dia structural topology.",

keywords = "Crystal structure, Metal-organic framework, SBUs, Topology, Zinc",

author = "Hui Yang and Li, \{Tie Hu\} and Yao Kang and Fei Wang",

year = "2012",

month = nov,

doi = "10.1016/j.inoche.2012.09.012",

language = "英语",

volume = "25",

pages = "92--95",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units for the construction of a metal-organic framework

AU - Yang, Hui

AU - Li, Tie Hu

AU - Kang, Yao

AU - Wang, Fei

PY - 2012/11

Y1 - 2012/11

N2 - A new three-dimensional (3D) metal-organic framework (MOF) {Zn 5(μ 3-OH) 2(obb) 4[(CH 3) 2NH] 2}·2DMF (1; H 2obb = 4,4′-oxybisbenzoic acid; DMF = N,N′-dimethyl formamide) with unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units (SBUs) has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Elemental analysis (EA) and Infrared Spectroscopy (IR). The unprecedented pentanuclear Zn 5(μ 3-OH) 2(COO -) 8 SBU was formed by two trimeric Zn 3(μ 3-OH)(COO -) 6 SBUs, which can be simplified as 4-connected node. Correspondingly, compound 1 exhibits dia structural topology.

AB - A new three-dimensional (3D) metal-organic framework (MOF) {Zn 5(μ 3-OH) 2(obb) 4[(CH 3) 2NH] 2}·2DMF (1; H 2obb = 4,4′-oxybisbenzoic acid; DMF = N,N′-dimethyl formamide) with unusual Zn 5(μ 3-OH) 2(COO -) 8 secondary building units (SBUs) has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA), Elemental analysis (EA) and Infrared Spectroscopy (IR). The unprecedented pentanuclear Zn 5(μ 3-OH) 2(COO -) 8 SBU was formed by two trimeric Zn 3(μ 3-OH)(COO -) 6 SBUs, which can be simplified as 4-connected node. Correspondingly, compound 1 exhibits dia structural topology.

KW - Crystal structure

KW - Metal-organic framework

KW - SBUs

KW - Topology

KW - Zinc

UR - https://www.scopus.com/pages/publications/84867558564

U2 - 10.1016/j.inoche.2012.09.012

DO - 10.1016/j.inoche.2012.09.012

M3 - 文章

AN - SCOPUS:84867558564

SN - 1387-7003

VL - 25

SP - 92

EP - 95

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Unusual Zn ₅(μ ₃-OH) ₂(COO ^-) ₈ secondary building units for the construction of a metal-organic framework

Abstract

Keywords

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