Unusual Cd 2(COO) 4Cl 2 building blocks for the construction of a dia or ths-type metal-organic framework

Hui Yang; Tie Hu Li; Yao Kang; Fei Wang

doi:10.1016/j.inoche.2012.02.007

Unusual Cd ₂(COO) ₄Cl ₂ building blocks for the construction of a dia or ths-type metal-organic framework

Hui Yang
, Tie Hu Li
, Yao Kang
, Fei Wang

School of Materials Sience and Engineering

Northwestern Polytechnical University Xian
CAS - Fujian Institute of Research on the Structure of Matter

Research output: Contribution to journal › Article › peer-review

1 Scopus citations

Abstract

A new three-dimensional (3D) metal-organic framework (MOF) [Cd(tpa)Cl](CH ₃) ₄ N ⁺ (1; tpa = 1, 4-terephthalic acid) with unusual Cd ₂ (COO) ₄Cl ₂ building block has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) Elemental analysis (EA) and Infrared Spectroscopy (IR). The Cd ₂(COO) ₄Cl ₂ building block can be simplified as 4-connected or two 3-connected nods in different ways, correspondingly, the compound 1 exhibits 4-connected dia or 3-connected ths structural topology.

Original language	English
Pages (from-to)	30-32
Number of pages	3
Journal	Inorganic Chemistry Communications
Volume	20
DOIs	https://doi.org/10.1016/j.inoche.2012.02.007
State	Published - Jun 2012

Keywords

Cadmium
Crystal structure
Metal-organic framework
SBUs
Topology

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10.1016/j.inoche.2012.02.007

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title = "Unusual Cd 2(COO) 4Cl 2 building blocks for the construction of a dia or ths-type metal-organic framework",

abstract = "A new three-dimensional (3D) metal-organic framework (MOF) [Cd(tpa)Cl](CH 3) 4 N + (1; tpa = 1, 4-terephthalic acid) with unusual Cd 2 (COO) 4Cl 2 building block has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) Elemental analysis (EA) and Infrared Spectroscopy (IR). The Cd 2(COO) 4Cl 2 building block can be simplified as 4-connected or two 3-connected nods in different ways, correspondingly, the compound 1 exhibits 4-connected dia or 3-connected ths structural topology.",

keywords = "Cadmium, Crystal structure, Metal-organic framework, SBUs, Topology",

author = "Hui Yang and Li, \{Tie Hu\} and Yao Kang and Fei Wang",

year = "2012",

month = jun,

doi = "10.1016/j.inoche.2012.02.007",

language = "英语",

volume = "20",

pages = "30--32",

journal = "Inorganic Chemistry Communications",

issn = "1387-7003",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Unusual Cd 2(COO) 4Cl 2 building blocks for the construction of a dia or ths-type metal-organic framework

AU - Yang, Hui

AU - Li, Tie Hu

AU - Kang, Yao

AU - Wang, Fei

PY - 2012/6

Y1 - 2012/6

N2 - A new three-dimensional (3D) metal-organic framework (MOF) [Cd(tpa)Cl](CH 3) 4 N + (1; tpa = 1, 4-terephthalic acid) with unusual Cd 2 (COO) 4Cl 2 building block has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) Elemental analysis (EA) and Infrared Spectroscopy (IR). The Cd 2(COO) 4Cl 2 building block can be simplified as 4-connected or two 3-connected nods in different ways, correspondingly, the compound 1 exhibits 4-connected dia or 3-connected ths structural topology.

AB - A new three-dimensional (3D) metal-organic framework (MOF) [Cd(tpa)Cl](CH 3) 4 N + (1; tpa = 1, 4-terephthalic acid) with unusual Cd 2 (COO) 4Cl 2 building block has been solvothermally synthesized and structurally characterized by the aid of single crystal X-ray diffraction, powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) Elemental analysis (EA) and Infrared Spectroscopy (IR). The Cd 2(COO) 4Cl 2 building block can be simplified as 4-connected or two 3-connected nods in different ways, correspondingly, the compound 1 exhibits 4-connected dia or 3-connected ths structural topology.

KW - Cadmium

KW - Crystal structure

KW - Metal-organic framework

KW - SBUs

KW - Topology

UR - https://www.scopus.com/pages/publications/84862800375

U2 - 10.1016/j.inoche.2012.02.007

DO - 10.1016/j.inoche.2012.02.007

M3 - 文章

AN - SCOPUS:84862800375

SN - 1387-7003

VL - 20

SP - 30

EP - 32

JO - Inorganic Chemistry Communications

JF - Inorganic Chemistry Communications

ER -

Unusual Cd ₂(COO) ₄Cl ₂ building blocks for the construction of a dia or ths-type metal-organic framework

Abstract

Keywords

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