Unprecedented side reactions in Stille coupling: Desired ones for Stille polycondensation

Hongyan Huang; Guanyuan Jiao; Shuli Liu; Quan Li; Xin Shi; Nina Fu; Lianhui Wang; Baomin Zhao; Wei Huang

doi:10.1039/c5cc05404d

Unprecedented side reactions in Stille coupling: Desired ones for Stille polycondensation

Hongyan Huang
, Guanyuan Jiao
, Shuli Liu
, Quan Li
, Xin Shi
, Nina Fu
, Lianhui Wang
, Baomin Zhao
, Wei Huang

Nanjing University of Posts and Telecommunications
Nanjing Tech University

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C-H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency.

Original language	English
Pages (from-to)	15846-15849
Number of pages	4
Journal	Chemical Communications
Volume	51
Issue number	87
DOIs	https://doi.org/10.1039/c5cc05404d
State	Published - 2015
Externally published	Yes

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10.1039/c5cc05404d

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title = "Unprecedented side reactions in Stille coupling: Desired ones for Stille polycondensation",

abstract = "Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C-H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency.",

author = "Hongyan Huang and Guanyuan Jiao and Shuli Liu and Quan Li and Xin Shi and Nina Fu and Lianhui Wang and Baomin Zhao and Wei Huang",

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T1 - Unprecedented side reactions in Stille coupling

T2 - Desired ones for Stille polycondensation

AU - Huang, Hongyan

AU - Jiao, Guanyuan

AU - Liu, Shuli

AU - Li, Quan

AU - Shi, Xin

AU - Fu, Nina

AU - Wang, Lianhui

AU - Zhao, Baomin

AU - Huang, Wei

PY - 2015

Y1 - 2015

N2 - Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C-H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency.

AB - Two types of unprecedented side reactions were identified in the Stille coupling reaction, including the direct C-H stannylation of the α-hydrogen of thiophene and the stannylation of arylbromides with trialkylstannane bromide. These results reveal the major source of enhancements for Stille polycondensation efficiency.

UR - https://www.scopus.com/pages/publications/84945973203

U2 - 10.1039/c5cc05404d

DO - 10.1039/c5cc05404d

M3 - 文章

AN - SCOPUS:84945973203

SN - 1359-7345

VL - 51

SP - 15846

EP - 15849

JO - Chemical Communications

JF - Chemical Communications

IS - 87

ER -

Unprecedented side reactions in Stille coupling: Desired ones for Stille polycondensation

Abstract

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