Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Wen Guan; Chao Xu; Yao Chen; Yanli Mao; Zhongxian Song; Binrong Li; Yongsheng Yan; Yunlei Zhang

doi:10.1039/d6cc02599d

Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Wen Guan
, Chao Xu
, Yao Chen
, Yanli Mao
, Zhongxian Song
, Binrong Li
, Yongsheng Yan
, Yunlei Zhang

Jiangsu University
Henan University of Urban Construction
Suzhou University of Science and Technology

Research output: Contribution to journal › Article › peer-review

Abstract

A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

Original language	English
Pages (from-to)	12352-12356
Number of pages	5
Journal	Chemical Communications
Volume	62
Issue number	49
DOIs	https://doi.org/10.1039/d6cc02599d
State	Published - 25 Jun 2026
Externally published	Yes

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10.1039/d6cc02599d

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title = "Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid",

abstract = "A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9\% FDCA yield with 92.9\% faradaic efficiency.",

author = "Wen Guan and Chao Xu and Yao Chen and Yanli Mao and Zhongxian Song and Binrong Li and Yongsheng Yan and Yunlei Zhang",

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year = "2026",

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TY - JOUR

T1 - Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

AU - Guan, Wen

AU - Xu, Chao

AU - Chen, Yao

AU - Mao, Yanli

AU - Song, Zhongxian

AU - Li, Binrong

AU - Yan, Yongsheng

AU - Zhang, Yunlei

PY - 2026/6/25

Y1 - 2026/6/25

N2 - A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

AB - A sulfur-doped nickel catalyst with tunable Ni–O/Ni–S coordination is developed for sustainable non-noble metal electrochemical oxidation of 5-hydroxymethylfurfural (HMF) to 2,5-furandicarboxylic acid (FDCA). Sulfur doping modulates the electronic environment of adjacent Ni atoms, thereby enhancing HMF–Ni interaction and achieving 99.9% FDCA yield with 92.9% faradaic efficiency.

UR - https://www.scopus.com/pages/publications/105041016665

U2 - 10.1039/d6cc02599d

DO - 10.1039/d6cc02599d

M3 - 文章

AN - SCOPUS:105041016665

SN - 1359-7345

VL - 62

SP - 12352

EP - 12356

JO - Chemical Communications

JF - Chemical Communications

IS - 49

ER -

Tuning Ni–O/Ni–S coordination for efficient electrocatalytic oxidation of 5-hydroxymethylfurfural to 2,5-furandicarboxylic acid

Abstract

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