Towards high areal capacitance, rate capability, and tailorable supercapacitors: Co₃O₄@polypyrrole core-shell nanorod bundle array electrodes

Flexible supercapacitors with high areal capacitance are a promising approach for wearable energy-storage technology due to the limitation of the surface area of the human body (about 2 m²). Meanwhile, a tolerance to deformation and mechanic damage is critical for wearable applications. However, it is still a challenge to achieve supercapacitors with outstanding electrochemical performance and wearability, simultaneously. To solve this problem, we report high-performance, flexible, and tailorable solid-state supercapacitors enabled by Co₃O₄@PPy nanorod bundle arrays immobilized on carbon fiber cloth (CFC). Furthermore, a solid-state asymmetric supercapacitor was assembled using a freestanding Co₃O₄@PPy electrode, a freestanding porous carbon electrode, and PVA gel electrolyte. Benefiting from a 3D structure and the synergetic contribution of the Co₃O₄ nanorods and electrically conductive PPy layer, the Co₃O₄@PPy electrode and our developed supercapacitor exhibit a high areal capacitance of 6.67 F cm^-2 at a current density of 2 mA cm^-2, and 2.47 F cm^-2 at 4 mA cm^-2, respectively, as well as excellent rate capability. More importantly, the solid-state supercapacitor can be tailored into several units and various shapes. Each unit retains its original electrochemical performance. This work provides a new route to wearable energy-storage technology.