Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

Xiu Juan Jiang; Miao Du; Yan Sun; Jian Hua Guo; Jin Shan Li

doi:10.1016/j.jssc.2009.09.004

Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

Xiu Juan Jiang, Miao Du, Yan Sun, Jian Hua Guo, Jin Shan Li

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M₂(μ-H₂O)(3,4-pybz)₄]_n (M^II=Mn^II for 1, Zn^II for 2, or Cd^II for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schläfli symbol of (3.4.5)(3².4⁴.5⁵.6².7²), whereas [Pb(3,4-pybz)₂]_n (4) shows a completely different 3-D (4².6)₂(4⁴.6².8⁹) framework, which represents a subnet of the (4,8)-connected fluorite lattice.

Original language	English
Pages (from-to)	3211-3214
Number of pages	4
Journal	Journal of Solid State Chemistry
Volume	182
Issue number	11
DOIs	https://doi.org/10.1016/j.jssc.2009.09.004
State	Published - Nov 2009
Externally published	Yes

Keywords

Fluorescence
Metal-organic frameworks
Mixed connectivity
Network topology
Thermal stability

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10.1016/j.jssc.2009.09.004

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title = "Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies",

abstract = "Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M2(μ-H2O)(3,4-pybz)4]n (MII=MnII for 1, ZnII for 2, or CdII for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schl{\"a}fli symbol of (3.4.5)(32.44.55.62.72), whereas [Pb(3,4-pybz)2]n (4) shows a completely different 3-D (42.6)2(44.62.89) framework, which represents a subnet of the (4,8)-connected fluorite lattice.",

keywords = "Fluorescence, Metal-organic frameworks, Mixed connectivity, Network topology, Thermal stability",

author = "Jiang, {Xiu Juan} and Miao Du and Yan Sun and Guo, {Jian Hua} and Li, {Jin Shan}",

year = "2009",

month = nov,

doi = "10.1016/j.jssc.2009.09.004",

language = "英语",

volume = "182",

pages = "3211--3214",

journal = "Journal of Solid State Chemistry",

issn = "0022-4596",

publisher = "Academic Press Inc.",

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TY - JOUR

T1 - Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

AU - Jiang, Xiu Juan

AU - Du, Miao

AU - Sun, Yan

AU - Guo, Jian Hua

AU - Li, Jin Shan

PY - 2009/11

Y1 - 2009/11

N2 - Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M2(μ-H2O)(3,4-pybz)4]n (MII=MnII for 1, ZnII for 2, or CdII for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schläfli symbol of (3.4.5)(32.44.55.62.72), whereas [Pb(3,4-pybz)2]n (4) shows a completely different 3-D (42.6)2(44.62.89) framework, which represents a subnet of the (4,8)-connected fluorite lattice.

AB - Reactions of different metal salts with 3-pyridin-4-yl-benzoic acid (3,4-Hpybz) under ambient condition afford a series of 3-D metal-organic frameworks with two new types of (3,6)-connected net topologies. In the isomorphic complexes [M2(μ-H2O)(3,4-pybz)4]n (MII=MnII for 1, ZnII for 2, or CdII for 3), the octahedral metal nodes are extended by the 3-connected pybz tectons to constitute 3-D arrays with the Schläfli symbol of (3.4.5)(32.44.55.62.72), whereas [Pb(3,4-pybz)2]n (4) shows a completely different 3-D (42.6)2(44.62.89) framework, which represents a subnet of the (4,8)-connected fluorite lattice.

KW - Fluorescence

KW - Metal-organic frameworks

KW - Mixed connectivity

KW - Network topology

KW - Thermal stability

UR - http://www.scopus.com/inward/record.url?scp=70350574728&partnerID=8YFLogxK

U2 - 10.1016/j.jssc.2009.09.004

DO - 10.1016/j.jssc.2009.09.004

M3 - 文章

AN - SCOPUS:70350574728

SN - 0022-4596

VL - 182

SP - 3211

EP - 3214

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

IS - 11

ER -

Three-dimensional (3-D) metal-organic frameworks with 3-pyridin-4-yl-benzoate defining new (3,6)-connected net topologies

Abstract

Keywords

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