Thermodynamic-kinetic relationship in Pd-based metallic glasses

Establishing a direct correlation between thermodynamic and kinetic behaviors in metallic glasses is of paramount importance, yet it remains an unresolved challenge in the field. Here, we conduct a comprehensive investigation on Pd-based metallic glasses, integrating dynamic mechanical analysis and differential scanning calorimetry to probe the interplay between mechanical relaxation and thermodynamic properties. Our results demonstrate that the temperature-dependent evolution of excess entropy remarkably parallels the kinetic spectrum, providing compelling evidence for a strong thermodynamic-kinetic relationship. Notably, we quantitatively explore the relationship between stress relaxation kinetics and excess entropy. This work provides new insights into the intrinsic coupling between thermodynamic disorder and mechanical relaxation behaviors in metallic glasses, offering a novel framework for understanding glass transition dynamics.