Thermal and mechanical properties of liquid-like trisilanol isobutyl-polyhedral oligomeric silsesquioxanes (POSS) derivative/epoxy nanocomposites

Haipeng Bai; Yaping Zheng; Ruilu Yang; Aibo Zhang; Nan Wang

doi:10.1002/pc.23628

Thermal and mechanical properties of liquid-like trisilanol isobutyl-polyhedral oligomeric silsesquioxanes (POSS) derivative/epoxy nanocomposites

Haipeng Bai
, Yaping Zheng
, Ruilu Yang
, Aibo Zhang
, Nan Wang

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

12 Scopus citations

Abstract

Liquid-like trisilanol isobutyl polyhedral oligomeric silsesquioxanes derivative (L-POSS-D) was synthesized with γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) as corona and polyetheramine M1000 as canopy. Its structure and properties were characterized by FTIR, XPS, TGA and Rheology data. Epoxy nanocomposites with 0.0, 0.5, 1.0 and 2.0 wt% content of L-POSS-D were prepared. T_g of the nanocomposites improved 47.6°C higher than pure epoxy resin. Mechanical properties, including flexural strength and impact toughness, were improved markedly with L-POSS-D. The morphologies of impact fracture were studied by SEM. POLYM. COMPOS., 38:691–698, 2017.

Original language	English
Pages (from-to)	691-698
Number of pages	8
Journal	Polymer Composites
Volume	38
Issue number	4
DOIs	https://doi.org/10.1002/pc.23628
State	Published - 1 Apr 2017

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title = "Thermal and mechanical properties of liquid-like trisilanol isobutyl-polyhedral oligomeric silsesquioxanes (POSS) derivative/epoxy nanocomposites",

abstract = "Liquid-like trisilanol isobutyl polyhedral oligomeric silsesquioxanes derivative (L-POSS-D) was synthesized with γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) as corona and polyetheramine M1000 as canopy. Its structure and properties were characterized by FTIR, XPS, TGA and Rheology data. Epoxy nanocomposites with 0.0, 0.5, 1.0 and 2.0 wt\% content of L-POSS-D were prepared. Tg of the nanocomposites improved 47.6°C higher than pure epoxy resin. Mechanical properties, including flexural strength and impact toughness, were improved markedly with L-POSS-D. The morphologies of impact fracture were studied by SEM. POLYM. COMPOS., 38:691–698, 2017.",

author = "Haipeng Bai and Yaping Zheng and Ruilu Yang and Aibo Zhang and Nan Wang",

note = "Publisher Copyright: {\textcopyright} 2015 Society of Plastics Engineers",

year = "2017",

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doi = "10.1002/pc.23628",

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T1 - Thermal and mechanical properties of liquid-like trisilanol isobutyl-polyhedral oligomeric silsesquioxanes (POSS) derivative/epoxy nanocomposites

AU - Bai, Haipeng

AU - Zheng, Yaping

AU - Yang, Ruilu

AU - Zhang, Aibo

AU - Wang, Nan

PY - 2017/4/1

Y1 - 2017/4/1

N2 - Liquid-like trisilanol isobutyl polyhedral oligomeric silsesquioxanes derivative (L-POSS-D) was synthesized with γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) as corona and polyetheramine M1000 as canopy. Its structure and properties were characterized by FTIR, XPS, TGA and Rheology data. Epoxy nanocomposites with 0.0, 0.5, 1.0 and 2.0 wt% content of L-POSS-D were prepared. Tg of the nanocomposites improved 47.6°C higher than pure epoxy resin. Mechanical properties, including flexural strength and impact toughness, were improved markedly with L-POSS-D. The morphologies of impact fracture were studied by SEM. POLYM. COMPOS., 38:691–698, 2017.

AB - Liquid-like trisilanol isobutyl polyhedral oligomeric silsesquioxanes derivative (L-POSS-D) was synthesized with γ-(2,3-epoxypropoxy)propytrimethoxysilane (KH560) as corona and polyetheramine M1000 as canopy. Its structure and properties were characterized by FTIR, XPS, TGA and Rheology data. Epoxy nanocomposites with 0.0, 0.5, 1.0 and 2.0 wt% content of L-POSS-D were prepared. Tg of the nanocomposites improved 47.6°C higher than pure epoxy resin. Mechanical properties, including flexural strength and impact toughness, were improved markedly with L-POSS-D. The morphologies of impact fracture were studied by SEM. POLYM. COMPOS., 38:691–698, 2017.

UR - https://www.scopus.com/pages/publications/84931048945

U2 - 10.1002/pc.23628

DO - 10.1002/pc.23628

M3 - 文章

AN - SCOPUS:84931048945

SN - 0272-8397

VL - 38

SP - 691

EP - 698

JO - Polymer Composites

JF - Polymer Composites

IS - 4

ER -

Thermal and mechanical properties of liquid-like trisilanol isobutyl-polyhedral oligomeric silsesquioxanes (POSS) derivative/epoxy nanocomposites

Abstract

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