Abstract
Willow or poplar catkins were carbonized to prepare carbon microtubes (CMTs) due to their natural micro-tubular structure. After carbonization at temperatures of 550-950 ° C, CMTs with outer and inner diameters of 4-8 and 3-7 lm were obtained. In addition to having a large and accessible inner tube, a small amount of nitrogen (∼ 1.8 at.%) and phosphorus (∼ 0.4 at.%) dopants cause CMTs prepared at 750 ° C to be a cheap metal-free catalyst with good catalytic activity in the oxygen reduction reaction.
Original language | English |
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Pages (from-to) | 5292-5297 |
Number of pages | 6 |
Journal | Carbon |
Volume | 49 |
Issue number | 15 |
DOIs | |
State | Published - Dec 2011 |
Externally published | Yes |