The production of carbon microtubes by the carbonization of catkins and their use in the oxygen reduction reaction

M. A. Yanwen, Jin Zhao, Lingrong Zhang, Yu Zhao, Quli Fan, Xing'ao Li, Zheng Hu, Wei Huang

Research output: Contribution to journalArticlepeer-review

74 Scopus citations

Abstract

Willow or poplar catkins were carbonized to prepare carbon microtubes (CMTs) due to their natural micro-tubular structure. After carbonization at temperatures of 550-950 ° C, CMTs with outer and inner diameters of 4-8 and 3-7 lm were obtained. In addition to having a large and accessible inner tube, a small amount of nitrogen (∼ 1.8 at.%) and phosphorus (∼ 0.4 at.%) dopants cause CMTs prepared at 750 ° C to be a cheap metal-free catalyst with good catalytic activity in the oxygen reduction reaction.

Original languageEnglish
Pages (from-to)5292-5297
Number of pages6
JournalCarbon
Volume49
Issue number15
DOIs
StatePublished - Dec 2011
Externally publishedYes

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