TY - JOUR
T1 - Synthesis, structure and electrochemical behavior of a 3D crystalline copper(II) metal-organic framework
AU - Bai, Hong Ye
AU - Fan, Wei Qiang
AU - Liu, Chun Bo
AU - Shi, Wei Dong
AU - Yan, Yong Sheng
PY - 2014/8
Y1 - 2014/8
N2 - Using an flexible amide-type tripodal ligand N,N',N"-tris(3-pyridyl)- 1,3,5-benzenetricarboxamide (L) and 1,4-benzenedicarboxylic acid (H 2bdc), a three-dimensional copper(II) metal-organic framework (MOF) formulated as [Cu(bdc)(L)]n has been hydrothermally synthesized and structurally characterized by IR, elemental, X-ray single-crystal diffraction and thermal analysis. The complex crystallizes in the triclinic, space group P - 1, a = 8.891(2) Å, b = 11.760(2) Å, c = 15.348(3) Å, α = 96.73(3)°, β = 105.96(3)°, γ = 106.47(3)°, V = 1446.2(5) Å3, Mr = 666.10, Dc = 1.530 g/cm 3, Z = 2, F(000) = 682, GOOF = 1.0560, μ(MoKα) = 0.817 mm-1, R = 0.0366 and wR = 0.0885. The structural analyses reveal that the title compound consists of one Cu(II) atom, two halves of bdc, and one L ligand. Each Cu(II) atom is linked by two bdc ligands and three L ligands to form a three-dimensional network. In addition, the electrochemical behavior of title compound has been studied. CCDC No. 990526.
AB - Using an flexible amide-type tripodal ligand N,N',N"-tris(3-pyridyl)- 1,3,5-benzenetricarboxamide (L) and 1,4-benzenedicarboxylic acid (H 2bdc), a three-dimensional copper(II) metal-organic framework (MOF) formulated as [Cu(bdc)(L)]n has been hydrothermally synthesized and structurally characterized by IR, elemental, X-ray single-crystal diffraction and thermal analysis. The complex crystallizes in the triclinic, space group P - 1, a = 8.891(2) Å, b = 11.760(2) Å, c = 15.348(3) Å, α = 96.73(3)°, β = 105.96(3)°, γ = 106.47(3)°, V = 1446.2(5) Å3, Mr = 666.10, Dc = 1.530 g/cm 3, Z = 2, F(000) = 682, GOOF = 1.0560, μ(MoKα) = 0.817 mm-1, R = 0.0366 and wR = 0.0885. The structural analyses reveal that the title compound consists of one Cu(II) atom, two halves of bdc, and one L ligand. Each Cu(II) atom is linked by two bdc ligands and three L ligands to form a three-dimensional network. In addition, the electrochemical behavior of title compound has been studied. CCDC No. 990526.
KW - crystal structure
KW - electrochemical behavior
KW - Hydrothermal synthesis
UR - http://www.scopus.com/inward/record.url?scp=84906095408&partnerID=8YFLogxK
U2 - 10.1142/S1793604714500490
DO - 10.1142/S1793604714500490
M3 - 文章
AN - SCOPUS:84906095408
SN - 1793-6047
VL - 7
JO - Functional Materials Letters
JF - Functional Materials Letters
IS - 4
M1 - 1450049
ER -