Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand

Wen Jin Zeng; Jin Fei Guo; Shuang Shuang Sun; Yong Hua Li; Jia Yi Zhu; Chao Huang; Shi Wang; Wei Huang

doi:10.1016/j.ica.2016.02.051

Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand

Wen Jin Zeng
, Jin Fei Guo
, Shuang Shuang Sun
, Yong Hua Li
, Jia Yi Zhu
, Chao Huang
, Shi Wang
, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Treatment of 1,2-C₆H₄(SiH₃)(SiH₃) (1) with [Pt(depe)(PEt₃)₂] (depe = Et₂PCH₂CH₂PEt₂) in the ratio of 1:1 yields the complex [Pt^II{1,2-C₆H₄(SiH₂)(SiH₂)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis.

Original language	English
Pages (from-to)	93-96
Number of pages	4
Journal	Inorganica Chimica Acta
Volume	446
DOIs	https://doi.org/10.1016/j.ica.2016.02.051
State	Published - 1 May 2016
Externally published	Yes

Keywords

Chelating
Multinuclear NMR
Platinum
Silyl

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10.1016/j.ica.2016.02.051

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title = "Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand",

abstract = "Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe = Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII\{1,2-C6H4(SiH2)(SiH2)\}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis.",

keywords = "Chelating, Multinuclear NMR, Platinum, Silyl",

author = "Zeng, \{Wen Jin\} and Guo, \{Jin Fei\} and Sun, \{Shuang Shuang\} and Li, \{Yong Hua\} and Zhu, \{Jia Yi\} and Chao Huang and Shi Wang and Wei Huang",

note = "Publisher Copyright: {\textcopyright} 2016 Elsevier B.V.",

year = "2016",

month = may,

day = "1",

doi = "10.1016/j.ica.2016.02.051",

language = "英语",

volume = "446",

pages = "93--96",

journal = "Inorganica Chimica Acta",

issn = "0020-1693",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand

AU - Zeng, Wen Jin

AU - Guo, Jin Fei

AU - Sun, Shuang Shuang

AU - Li, Yong Hua

AU - Zhu, Jia Yi

AU - Huang, Chao

AU - Wang, Shi

AU - Huang, Wei

PY - 2016/5/1

Y1 - 2016/5/1

N2 - Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe = Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII{1,2-C6H4(SiH2)(SiH2)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis.

AB - Treatment of 1,2-C6H4(SiH3)(SiH3) (1) with [Pt(depe)(PEt3)2] (depe = Et2PCH2CH2PEt2) in the ratio of 1:1 yields the complex [PtII{1,2-C6H4(SiH2)(SiH2)}(depe)] (2), which has unique reactivity towards sterically unhindered alcohol to form an unusual tetra-alkoxy substituted silyl platinum(II) compound (3). Only 2 examples of bis(silyl)platinum(II) complexes prepared from this chelating hydrosilane ligand have been registered in the Cambridge Structural Database. The structure of complex (3) was unambiguously determined by multinuclear NMR spectroscopic studies and single crystal X-ray analysis.

KW - Chelating

KW - Multinuclear NMR

KW - Platinum

KW - Silyl

UR - https://www.scopus.com/pages/publications/85044384797

U2 - 10.1016/j.ica.2016.02.051

DO - 10.1016/j.ica.2016.02.051

M3 - 文章

AN - SCOPUS:85044384797

SN - 0020-1693

VL - 446

SP - 93

EP - 96

JO - Inorganica Chimica Acta

JF - Inorganica Chimica Acta

ER -

Synthesis, structural characterization and reactivity towards methanol of a bis(silyl)platinum(II) complex bearing a chelating depe ligand

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Keywords

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