Synthesis of Ideal Energetic Materials with High Density and Performance Based on 5-Aminotetrazole

Caijin Lei; Hongwei Yang; Wei Yang; Qinghua Zhang; Guangbin Cheng

doi:10.1021/acs.cgd.2c00058

Synthesis of Ideal Energetic Materials with High Density and Performance Based on 5-Aminotetrazole

Caijin Lei
, Hongwei Yang
, Wei Yang
, Qinghua Zhang
, Guangbin Cheng

Nanjing University of Science and Technology
China Academy of Engineering Physics

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

In this study, a series of energetic compounds featuring intramolecular hydrogen bonds were demonstrated by the substituted reaction with 5-aminotetrazole. Notably, the representative energetic compounds 3 and 6 exhibit high density (1.910 g cm^-3and 1.905 g cm^-3) and good detonation properties (3: D = 9072 m s^-1, P = 37.1 GPa, 6: D = 8861 m s^-1, P = 32.3 GPa). Additionally, combining a series of other advantages such as simple preparation, good thermostability (T_d= 265 °C), and insensitivity (IS > 40 J, FS > 360 N), compound 6 is an ideal insensitive HEDM candidate.

Original language	English
Pages (from-to)	2594-2601
Number of pages	8
Journal	Crystal Growth and Design
Volume	22
Issue number	4
DOIs	https://doi.org/10.1021/acs.cgd.2c00058
State	Published - 6 Apr 2022
Externally published	Yes

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10.1021/acs.cgd.2c00058

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title = "Synthesis of Ideal Energetic Materials with High Density and Performance Based on 5-Aminotetrazole",

abstract = "In this study, a series of energetic compounds featuring intramolecular hydrogen bonds were demonstrated by the substituted reaction with 5-aminotetrazole. Notably, the representative energetic compounds 3 and 6 exhibit high density (1.910 g cm-3and 1.905 g cm-3) and good detonation properties (3: D = 9072 m s-1, P = 37.1 GPa, 6: D = 8861 m s-1, P = 32.3 GPa). Additionally, combining a series of other advantages such as simple preparation, good thermostability (Td= 265 °C), and insensitivity (IS > 40 J, FS > 360 N), compound 6 is an ideal insensitive HEDM candidate.",

author = "Caijin Lei and Hongwei Yang and Wei Yang and Qinghua Zhang and Guangbin Cheng",

year = "2022",

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day = "6",

doi = "10.1021/acs.cgd.2c00058",

language = "英语",

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journal = "Crystal Growth and Design",

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TY - JOUR

T1 - Synthesis of Ideal Energetic Materials with High Density and Performance Based on 5-Aminotetrazole

AU - Lei, Caijin

AU - Yang, Hongwei

AU - Yang, Wei

AU - Zhang, Qinghua

AU - Cheng, Guangbin

PY - 2022/4/6

Y1 - 2022/4/6

N2 - In this study, a series of energetic compounds featuring intramolecular hydrogen bonds were demonstrated by the substituted reaction with 5-aminotetrazole. Notably, the representative energetic compounds 3 and 6 exhibit high density (1.910 g cm-3and 1.905 g cm-3) and good detonation properties (3: D = 9072 m s-1, P = 37.1 GPa, 6: D = 8861 m s-1, P = 32.3 GPa). Additionally, combining a series of other advantages such as simple preparation, good thermostability (Td= 265 °C), and insensitivity (IS > 40 J, FS > 360 N), compound 6 is an ideal insensitive HEDM candidate.

AB - In this study, a series of energetic compounds featuring intramolecular hydrogen bonds were demonstrated by the substituted reaction with 5-aminotetrazole. Notably, the representative energetic compounds 3 and 6 exhibit high density (1.910 g cm-3and 1.905 g cm-3) and good detonation properties (3: D = 9072 m s-1, P = 37.1 GPa, 6: D = 8861 m s-1, P = 32.3 GPa). Additionally, combining a series of other advantages such as simple preparation, good thermostability (Td= 265 °C), and insensitivity (IS > 40 J, FS > 360 N), compound 6 is an ideal insensitive HEDM candidate.

UR - https://www.scopus.com/pages/publications/85127410358

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DO - 10.1021/acs.cgd.2c00058

M3 - 文章

AN - SCOPUS:85127410358

SN - 1528-7483

VL - 22

SP - 2594

EP - 2601

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 4

ER -

Synthesis of Ideal Energetic Materials with High Density and Performance Based on 5-Aminotetrazole

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