Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

Zhiyong He; Jun Luo; Chunxu Lü; Rong Xu; Jinshan Li

Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

Zhiyong He, Jun Luo, Chunxu Lü, Rong Xu, Jinshan Li

Research output: Contribution to journal › Article › peer-review

13 Scopus citations

Abstract

The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et ₃NH] HSO ₄ was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

Original language	English
Pages (from-to)	83-92
Number of pages	10
Journal	Central European Journal of Energetic Materials
Volume	8
Issue number	2
State	Published - 2011
Externally published	Yes

Keywords

DPT
HMX
Ionic liquid
Nitrolysis

Cite this

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title = "Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids",

abstract = "The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61\% against 45\% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.",

keywords = "DPT, HMX, Ionic liquid, Nitrolysis",

author = "Zhiyong He and Jun Luo and Chunxu L{\"u} and Rong Xu and Jinshan Li",

year = "2011",

language = "英语",

volume = "8",

pages = "83--92",

journal = "Central European Journal of Energetic Materials",

issn = "1733-7178",

publisher = "Institute of Industrial Organic Chemistry",

number = "2",

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TY - JOUR

T1 - Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

AU - He, Zhiyong

AU - Luo, Jun

AU - Lü, Chunxu

AU - Xu, Rong

AU - Li, Jinshan

PY - 2011

Y1 - 2011

N2 - The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

AB - The direct nitrolysis of DPT to synthesize HMX with ionic liquids (ILs) as catalysts was investigated. The results showed that [Et 3NH] HSO 4 was the best catalyst among 18 ILs used and the yield of HMX was up to 61% against 45% without IL. The ILs could be efficiently recovered by simple distillation and extraction after reaction without any apparent loss of catalytic activity even after 10 times recycling.

KW - DPT

KW - HMX

KW - Ionic liquid

KW - Nitrolysis

UR - https://www.scopus.com/pages/publications/83055193335

M3 - 文章

AN - SCOPUS:83055193335

SN - 1733-7178

VL - 8

SP - 83

EP - 92

JO - Central European Journal of Energetic Materials

JF - Central European Journal of Energetic Materials

IS - 2

ER -

Synthesis of HMX via Nitrolysis of DPT Catalyzed by acidic ionic liquids

Abstract

Keywords

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