Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

Guiqin Yu; Shiqiang Yan; Feng Zhou; Xuqing Liu; Weimin Liu; Yongmin Liang

doi:10.1007/s11249-006-9167-8

Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

Guiqin Yu, Shiqiang Yan, Feng Zhou, Xuqing Liu, Weimin Liu, Yongmin Liang

Research output: Contribution to journal › Article › peer-review

103 Scopus citations

Abstract

A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3-methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 °C and good tribological properties.

Original language	English
Pages (from-to)	197-205
Number of pages	9
Journal	Tribology Letters
Volume	25
Issue number	3
DOIs	https://doi.org/10.1007/s11249-006-9167-8
State	Published - Mar 2007
Externally published	Yes

Keywords

EDS
Film thickness
SEM
Solid lubrication
Steel
Thermal stability

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10.1007/s11249-006-9167-8

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abstract = "A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3-methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 °C and good tribological properties.",

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author = "Guiqin Yu and Shiqiang Yan and Feng Zhou and Xuqing Liu and Weimin Liu and Yongmin Liang",

year = "2007",

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doi = "10.1007/s11249-006-9167-8",

language = "英语",

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pages = "197--205",

journal = "Tribology Letters",

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TY - JOUR

T1 - Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

AU - Yu, Guiqin

AU - Yan, Shiqiang

AU - Zhou, Feng

AU - Liu, Xuqing

AU - Liu, Weimin

AU - Liang, Yongmin

PY - 2007/3

Y1 - 2007/3

N2 - A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3-methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 °C and good tribological properties.

AB - A new series of novel dicationic symmetrical and asymmetrical ionic liquids (ILs) consisting of tributylalkyl phosphonium and alkylimidazolium were synthesized. Their tribological properties in the form of spin-coated ultra-thin films sliding against AISI-52100 steel ball were studied in a ball-on-plate configuration on a Universal Micro-tribometer-2MT tester, using perfluoropolyether (PFPE) and normal ILs as comparisons. The best result is obtained for asymmetrical 1-(1-tributylphosphine-yl-hexyl)-3-methylimidazolium dihexafluorophosphate, which has very high decomposition temperature-about 450 °C and good tribological properties.

KW - EDS

KW - Film thickness

KW - SEM

KW - Solid lubrication

KW - Steel

KW - Thermal stability

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DO - 10.1007/s11249-006-9167-8

M3 - 文章

AN - SCOPUS:33847285941

SN - 1023-8883

VL - 25

SP - 197

EP - 205

JO - Tribology Letters

JF - Tribology Letters

IS - 3

ER -

Synthesis of dicationic symmetrical and asymmetrical ionic liquids and their tribological properties as ultrathin films

Abstract

Keywords

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