Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)3] -

Shi Wang; Xuehua Ding; Wenrui He; Wei Huang

doi:10.1007/s10870-010-9965-6

Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)₃] ^-

Shi Wang
, Xuehua Ding
, Wenrui He
, Wei Huang

Nanjing University of Posts and Telecommunications

Research output: Contribution to journal › Article › peer-review

Abstract

By using a pre-designed anionic precursor [TpFe^III(CN) ₃]^- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)₂Fe ₂ ^III (CN) ₆Zn•2H₂O] _n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFe^III(CN) ₃]^- unit acts as a bridging bidentate ligand toward two Zn²⁺ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)₂Fe ₂ ^III (CN) ₆Zn•2H₂O] _n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFe^III(CN)₃]^- unit acts as a bridging bidentate ligand toward two Zn²⁺ atoms through two of its three cyanide groups.

Original language	English
Pages (from-to)	737-741
Number of pages	5
Journal	Journal of Chemical Crystallography
Volume	41
Issue number	5
DOIs	https://doi.org/10.1007/s10870-010-9965-6
State	Published - May 2011
Externally published	Yes

Keywords

Cyanides
Heterometallic complexes
Iron
Zinc

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10.1007/s10870-010-9965-6

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@article{89d5be6b1aab4f11b76080d96169407d,

title = "Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)3] -",

abstract = "By using a pre-designed anionic precursor [TpFeIII(CN) 3]- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, M{\"o}ssbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) {\AA}, b = 18.3003(10) {\AA}, c = 12.9855(7) {\AA} and consists of rhombic chains, in which the [TpFeIII(CN) 3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.",

keywords = "Cyanides, Heterometallic complexes, Iron, Zinc",

author = "Shi Wang and Xuehua Ding and Wenrui He and Wei Huang",

year = "2011",

month = may,

doi = "10.1007/s10870-010-9965-6",

language = "英语",

volume = "41",

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journal = "Journal of Chemical Crystallography",

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TY - JOUR

T1 - Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)3] -

AU - Wang, Shi

AU - Ding, Xuehua

AU - He, Wenrui

AU - Huang, Wei

PY - 2011/5

Y1 - 2011/5

N2 - By using a pre-designed anionic precursor [TpFeIII(CN) 3]- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFeIII(CN) 3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.

AB - By using a pre-designed anionic precursor [TpFeIII(CN) 3]- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFeIII(CN) 3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.

KW - Cyanides

KW - Heterometallic complexes

KW - Iron

KW - Zinc

UR - https://www.scopus.com/pages/publications/79955889392

U2 - 10.1007/s10870-010-9965-6

DO - 10.1007/s10870-010-9965-6

M3 - 文章

AN - SCOPUS:79955889392

SN - 1074-1542

VL - 41

SP - 737

EP - 741

JO - Journal of Chemical Crystallography

JF - Journal of Chemical Crystallography

IS - 5

ER -

Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)₃] ^-

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