TY - JOUR
T1 - Synthesis, characterization and crystal structure of a new one-dimensional heterobimetallic coordination polymer based on [(Tp)Fe(CN)3] -
AU - Wang, Shi
AU - Ding, Xuehua
AU - He, Wenrui
AU - Huang, Wei
PY - 2011/5
Y1 - 2011/5
N2 - By using a pre-designed anionic precursor [TpFeIII(CN) 3]- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFeIII(CN) 3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.
AB - By using a pre-designed anionic precursor [TpFeIII(CN) 3]- (Tp = hydrotris(pyrazolyl)borate) as a structural building block, a new cyanide-bridged one-dimensional heterobimetallic coordination polymer, [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) has been prepared and characterized by X-ray single crystal diffraction, Mössbauer and magnetic experiments. Complex I crystallizes in the orthorhombic Ibam space group with a = 14.4094(8) Å, b = 18.3003(10) Å, c = 12.9855(7) Å and consists of rhombic chains, in which the [TpFeIII(CN) 3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups. Graphical Abstract: [(Tp)2Fe 2 III (CN) 6Zn•2H2O] n (I) crystallizes in the orthorhombic Ibam space group and consists of rhombic chains, in which the [TpFeIII(CN)3]- unit acts as a bridging bidentate ligand toward two Zn2+ atoms through two of its three cyanide groups.
KW - Cyanides
KW - Heterometallic complexes
KW - Iron
KW - Zinc
UR - http://www.scopus.com/inward/record.url?scp=79955889392&partnerID=8YFLogxK
U2 - 10.1007/s10870-010-9965-6
DO - 10.1007/s10870-010-9965-6
M3 - 文章
AN - SCOPUS:79955889392
SN - 1074-1542
VL - 41
SP - 737
EP - 741
JO - Journal of Chemical Crystallography
JF - Journal of Chemical Crystallography
IS - 5
ER -