Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

Guang Wei Zhang; Qu Li Fan; Wei Huang

Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

Guang Wei Zhang
, Qu Li Fan
, Wei Huang

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of ¹H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)₆^4- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

Original language	English
Pages (from-to)	413-416
Number of pages	4
Journal	Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities
Volume	30
Issue number	2
State	Published - Feb 2009
Externally published	Yes

Keywords

Conjugated polyelectrolytes
Poly(p-phenylenevinylene)
Quenching effect

Cite this

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title = "Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer",

abstract = "A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30\% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.",

keywords = "Conjugated polyelectrolytes, Poly(p-phenylenevinylene), Quenching effect",

author = "Zhang, \{Guang Wei\} and Fan, \{Qu Li\} and Wei Huang",

year = "2009",

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T1 - Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

AU - Zhang, Guang Wei

AU - Fan, Qu Li

AU - Huang, Wei

PY - 2009/2

Y1 - 2009/2

N2 - A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

AB - A novel poly(p-phenylenevinylene) related copolymer was synthesized by Wittig reaction. The corresponding cationic conjugated polymer was successfully obtained via a post-polymerization approach. On the basis of 1H NMR spectra, it was found that this phenyl-substituted PPV related copolymer is of 30% cis-vinylic linkage. The quenching effect of Fe(CN)64- on the cationic PPV derivative was studied, and a downward Stern-Volmer curve was found.

KW - Conjugated polyelectrolytes

KW - Poly(p-phenylenevinylene)

KW - Quenching effect

UR - https://www.scopus.com/pages/publications/64749095449

M3 - 文章

AN - SCOPUS:64749095449

SN - 0251-0790

VL - 30

SP - 413

EP - 416

JO - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

JF - Gaodeng Xuexiao Huaxue Xuebao/Chemical Journal of Chinese Universities

IS - 2

ER -

Synthesis and quenching behavior of a novel cationic poly(p-phenylenevinylene) related copolymer

Abstract

Keywords

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