Synthesis and properties of low-surface-energy polyimides

Hai Zhong Wang; Qian Ye; Xiao Long Wang

doi:10.1246/cl.140825

Synthesis and properties of low-surface-energy polyimides

Hai Zhong Wang, Qian Ye, Xiao Long Wang

CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

Abstract

An aromatic diamine monomer, 1H,1H-perfluorooctyl 3,5-diaminobenzoate (PFD), was synthesized in three steps, which was used to prepare the polyimides containing pendant perfluoroalkyl chains via the polymerization of PFD with commercial 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Various characterization techniques including thermogravimetric analysis, infrared spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the new polyimides with perfluoroalkyl chains. The resulting polyimide film exhibits hydrophobicity with a contact angle of 95° for water, and the calculated surface free energy is 37.4mNm^-1. Superhydrophobic surfaces were also demonstrated by coating the polyimide containing pendant perfluorooctyl chains on rough alumina substrate.

Original language	English
Pages (from-to)	1926-1928
Number of pages	3
Journal	Chemistry Letters
Volume	43
Issue number	12
DOIs	https://doi.org/10.1246/cl.140825
State	Published - 2014
Externally published	Yes

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title = "Synthesis and properties of low-surface-energy polyimides",

abstract = "An aromatic diamine monomer, 1H,1H-perfluorooctyl 3,5-diaminobenzoate (PFD), was synthesized in three steps, which was used to prepare the polyimides containing pendant perfluoroalkyl chains via the polymerization of PFD with commercial 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Various characterization techniques including thermogravimetric analysis, infrared spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the new polyimides with perfluoroalkyl chains. The resulting polyimide film exhibits hydrophobicity with a contact angle of 95° for water, and the calculated surface free energy is 37.4mNm-1. Superhydrophobic surfaces were also demonstrated by coating the polyimide containing pendant perfluorooctyl chains on rough alumina substrate.",

author = "Wang, {Hai Zhong} and Qian Ye and Wang, {Xiao Long}",

note = "Publisher Copyright: {\textcopyright} 2014 The Chemical Society of Japan.",

year = "2014",

doi = "10.1246/cl.140825",

language = "英语",

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T1 - Synthesis and properties of low-surface-energy polyimides

AU - Wang, Hai Zhong

AU - Ye, Qian

AU - Wang, Xiao Long

PY - 2014

Y1 - 2014

N2 - An aromatic diamine monomer, 1H,1H-perfluorooctyl 3,5-diaminobenzoate (PFD), was synthesized in three steps, which was used to prepare the polyimides containing pendant perfluoroalkyl chains via the polymerization of PFD with commercial 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Various characterization techniques including thermogravimetric analysis, infrared spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the new polyimides with perfluoroalkyl chains. The resulting polyimide film exhibits hydrophobicity with a contact angle of 95° for water, and the calculated surface free energy is 37.4mNm-1. Superhydrophobic surfaces were also demonstrated by coating the polyimide containing pendant perfluorooctyl chains on rough alumina substrate.

AB - An aromatic diamine monomer, 1H,1H-perfluorooctyl 3,5-diaminobenzoate (PFD), was synthesized in three steps, which was used to prepare the polyimides containing pendant perfluoroalkyl chains via the polymerization of PFD with commercial 4,4′-(hexafluoroisopropylidene)diphthalic anhydride. Various characterization techniques including thermogravimetric analysis, infrared spectroscopy, and X-ray photoelectron spectroscopy were used to characterize the new polyimides with perfluoroalkyl chains. The resulting polyimide film exhibits hydrophobicity with a contact angle of 95° for water, and the calculated surface free energy is 37.4mNm-1. Superhydrophobic surfaces were also demonstrated by coating the polyimide containing pendant perfluorooctyl chains on rough alumina substrate.

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DO - 10.1246/cl.140825

M3 - 文章

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SN - 0366-7022

VL - 43

SP - 1926

EP - 1928

JO - Chemistry Letters

JF - Chemistry Letters

IS - 12

ER -

Synthesis and properties of low-surface-energy polyimides

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