Synthesis and characterization of symmetric cyclooctatetraindoles: Exploring the potential as electron-rich skeletons with extended π-systems

Fang Wang; Xiang Chun Li; Wen Yong Lai; Yao Chen; Wei Huang; Fred Wudl

doi:10.1021/ol501083d

Synthesis and characterization of symmetric cyclooctatetraindoles: Exploring the potential as electron-rich skeletons with extended π-systems

Fang Wang, Xiang Chun Li, Wen Yong Lai, Yao Chen, Wei Huang, Fred Wudl

Research output: Contribution to journal › Article › peer-review

46 Scopus citations

Abstract

A facile one-pot tetramerization of indolin-2-one with phosphoryl chloride was applied for the first convenient direct synthesis of C_2v- symmetric cyclooctatetraindole with an 8π annulene as the center. Tetra- and octa-arylated cyclooctatetraindole derivatives functionalized with fluorescent fluorene and pyrene units were thus facilely synthesized and characterized.

Original language	English
Pages (from-to)	2942-2945
Number of pages	4
Journal	Organic Letters
Volume	16
Issue number	11
DOIs	https://doi.org/10.1021/ol501083d
State	Published - 6 Jun 2014
Externally published	Yes

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title = "Synthesis and characterization of symmetric cyclooctatetraindoles: Exploring the potential as electron-rich skeletons with extended π-systems",

abstract = "A facile one-pot tetramerization of indolin-2-one with phosphoryl chloride was applied for the first convenient direct synthesis of C2v- symmetric cyclooctatetraindole with an 8π annulene as the center. Tetra- and octa-arylated cyclooctatetraindole derivatives functionalized with fluorescent fluorene and pyrene units were thus facilely synthesized and characterized.",

author = "Fang Wang and Li, \{Xiang Chun\} and Lai, \{Wen Yong\} and Yao Chen and Wei Huang and Fred Wudl",

year = "2014",

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doi = "10.1021/ol501083d",

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journal = "Organic Letters",

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T1 - Synthesis and characterization of symmetric cyclooctatetraindoles

T2 - Exploring the potential as electron-rich skeletons with extended π-systems

AU - Wang, Fang

AU - Li, Xiang Chun

AU - Lai, Wen Yong

AU - Chen, Yao

AU - Huang, Wei

AU - Wudl, Fred

PY - 2014/6/6

Y1 - 2014/6/6

N2 - A facile one-pot tetramerization of indolin-2-one with phosphoryl chloride was applied for the first convenient direct synthesis of C2v- symmetric cyclooctatetraindole with an 8π annulene as the center. Tetra- and octa-arylated cyclooctatetraindole derivatives functionalized with fluorescent fluorene and pyrene units were thus facilely synthesized and characterized.

AB - A facile one-pot tetramerization of indolin-2-one with phosphoryl chloride was applied for the first convenient direct synthesis of C2v- symmetric cyclooctatetraindole with an 8π annulene as the center. Tetra- and octa-arylated cyclooctatetraindole derivatives functionalized with fluorescent fluorene and pyrene units were thus facilely synthesized and characterized.

UR - https://www.scopus.com/pages/publications/84902095835

U2 - 10.1021/ol501083d

DO - 10.1021/ol501083d

M3 - 文章

C2 - 24848438

AN - SCOPUS:84902095835

SN - 1523-7060

VL - 16

SP - 2942

EP - 2945

JO - Organic Letters

JF - Organic Letters

IS - 11

ER -

Synthesis and characterization of symmetric cyclooctatetraindoles: Exploring the potential as electron-rich skeletons with extended π-systems

Abstract

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