Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework

Xutong Yang; Shuguang Fan; Ying Li; Yongqiang Guo; Yunge Li; Kunpeng Ruan; Shengmao Zhang; Junliang Zhang; Jie Kong; Junwei Gu

doi:10.1016/j.compositesa.2019.105670

Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework

Xutong Yang
, Shuguang Fan
, Ying Li
, Yongqiang Guo
, Yunge Li
, Kunpeng Ruan
, Shengmao Zhang
, Junliang Zhang
, Jie Kong
, Junwei Gu

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian
Henan University
Xi'an University of Science and Technology
Queen Mary University of London
Henan University of Science and Technology

Research output: Contribution to journal › Article › peer-review

615 Scopus citations

Abstract

3D copper nanowires-thermally annealed graphene aerogel (CuNWs-TAGA) framework is firstly prepared by freeze-drying followed by thermal annealing from CuNWs, graphene oxide (GO) and L-ascorbic acid. Epoxy resin is then poured back into the above 3D CuNWs-TAGA framework to fabricate the CuNWs-TAGA/epoxy nanocomposites. CuNWs with average diameter of about 120 nm and length of approximate 10 μm are successfully prepared. When the mass fraction of CuNWs-TAGA is 7.2 wt% (6.0–1.2 wt% CuNWs-TAGA), the thermal conductivity coefficient (λ) value of the CuNWs-TAGA/epoxy nanocomposites reaches the maximum of 0.51 W/mK. Meantime, the CuNWs-TAGA/epoxy nanocomposites exhibit the maximum electromagnetic interference shielding effectiveness (EMI SE) value of 47 dB and electrical conductivity (σ) of 120.8 S/m, ascribed to perfect 3D CuNWs-TAGA conductive network structures. Meanwhile, the corresponding elasticity modulus, hardness, glass transition temperature (T_g) and heat-resistance index (T_HRI) of the CuNWs-TAGA/epoxy nanocomposites increase to 4.69 GPa, 0.33 GPa, 126.3 °C and 181.7 °C, respectively.

Original language	English
Article number	105670
Journal	Composites Part A: Applied Science and Manufacturing
Volume	128
DOIs	https://doi.org/10.1016/j.compositesa.2019.105670
State	Published - Jan 2020

Keywords

A. Polymer-matrix composites (PMCs)
B. Thermal properties
C. Electron microscopy
D. Casting

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10.1016/j.compositesa.2019.105670

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Yang, X., Fan, S., Li, Y., Guo, Y., Li, Y., Ruan, K., Zhang, S., Zhang, J., Kong, J., & Gu, J. (2020). Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework. Composites Part A: Applied Science and Manufacturing, 128, Article 105670. https://doi.org/10.1016/j.compositesa.2019.105670

@article{c94d9f33fe5e47c4bdfe07c1d018c6f2,

title = "Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework",

abstract = "3D copper nanowires-thermally annealed graphene aerogel (CuNWs-TAGA) framework is firstly prepared by freeze-drying followed by thermal annealing from CuNWs, graphene oxide (GO) and L-ascorbic acid. Epoxy resin is then poured back into the above 3D CuNWs-TAGA framework to fabricate the CuNWs-TAGA/epoxy nanocomposites. CuNWs with average diameter of about 120 nm and length of approximate 10 μm are successfully prepared. When the mass fraction of CuNWs-TAGA is 7.2 wt\% (6.0–1.2 wt\% CuNWs-TAGA), the thermal conductivity coefficient (λ) value of the CuNWs-TAGA/epoxy nanocomposites reaches the maximum of 0.51 W/mK. Meantime, the CuNWs-TAGA/epoxy nanocomposites exhibit the maximum electromagnetic interference shielding effectiveness (EMI SE) value of 47 dB and electrical conductivity (σ) of 120.8 S/m, ascribed to perfect 3D CuNWs-TAGA conductive network structures. Meanwhile, the corresponding elasticity modulus, hardness, glass transition temperature (Tg) and heat-resistance index (THRI) of the CuNWs-TAGA/epoxy nanocomposites increase to 4.69 GPa, 0.33 GPa, 126.3 °C and 181.7 °C, respectively.",

keywords = "A. Polymer-matrix composites (PMCs), B. Thermal properties, C. Electron microscopy, D. Casting",

author = "Xutong Yang and Shuguang Fan and Ying Li and Yongqiang Guo and Yunge Li and Kunpeng Ruan and Shengmao Zhang and Junliang Zhang and Jie Kong and Junwei Gu",

note = "Publisher Copyright: {\textcopyright} 2019 Elsevier Ltd",

year = "2020",

month = jan,

doi = "10.1016/j.compositesa.2019.105670",

language = "英语",

volume = "128",

journal = "Composites Part A: Applied Science and Manufacturing",

issn = "1359-835X",

publisher = "Elsevier Ltd",

}

Yang, X, Fan, S, Li, Y, Guo, Y, Li, Y, Ruan, K, Zhang, S, Zhang, J , Kong, J & Gu, J 2020, 'Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework', Composites Part A: Applied Science and Manufacturing, vol. 128, 105670. https://doi.org/10.1016/j.compositesa.2019.105670

Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework. / Yang, Xutong; Fan, Shuguang; Li, Ying et al.
In: Composites Part A: Applied Science and Manufacturing, Vol. 128, 105670, 01.2020.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework

AU - Yang, Xutong

AU - Fan, Shuguang

AU - Li, Ying

AU - Guo, Yongqiang

AU - Li, Yunge

AU - Ruan, Kunpeng

AU - Zhang, Shengmao

AU - Zhang, Junliang

AU - Kong, Jie

AU - Gu, Junwei

PY - 2020/1

Y1 - 2020/1

N2 - 3D copper nanowires-thermally annealed graphene aerogel (CuNWs-TAGA) framework is firstly prepared by freeze-drying followed by thermal annealing from CuNWs, graphene oxide (GO) and L-ascorbic acid. Epoxy resin is then poured back into the above 3D CuNWs-TAGA framework to fabricate the CuNWs-TAGA/epoxy nanocomposites. CuNWs with average diameter of about 120 nm and length of approximate 10 μm are successfully prepared. When the mass fraction of CuNWs-TAGA is 7.2 wt% (6.0–1.2 wt% CuNWs-TAGA), the thermal conductivity coefficient (λ) value of the CuNWs-TAGA/epoxy nanocomposites reaches the maximum of 0.51 W/mK. Meantime, the CuNWs-TAGA/epoxy nanocomposites exhibit the maximum electromagnetic interference shielding effectiveness (EMI SE) value of 47 dB and electrical conductivity (σ) of 120.8 S/m, ascribed to perfect 3D CuNWs-TAGA conductive network structures. Meanwhile, the corresponding elasticity modulus, hardness, glass transition temperature (Tg) and heat-resistance index (THRI) of the CuNWs-TAGA/epoxy nanocomposites increase to 4.69 GPa, 0.33 GPa, 126.3 °C and 181.7 °C, respectively.

AB - 3D copper nanowires-thermally annealed graphene aerogel (CuNWs-TAGA) framework is firstly prepared by freeze-drying followed by thermal annealing from CuNWs, graphene oxide (GO) and L-ascorbic acid. Epoxy resin is then poured back into the above 3D CuNWs-TAGA framework to fabricate the CuNWs-TAGA/epoxy nanocomposites. CuNWs with average diameter of about 120 nm and length of approximate 10 μm are successfully prepared. When the mass fraction of CuNWs-TAGA is 7.2 wt% (6.0–1.2 wt% CuNWs-TAGA), the thermal conductivity coefficient (λ) value of the CuNWs-TAGA/epoxy nanocomposites reaches the maximum of 0.51 W/mK. Meantime, the CuNWs-TAGA/epoxy nanocomposites exhibit the maximum electromagnetic interference shielding effectiveness (EMI SE) value of 47 dB and electrical conductivity (σ) of 120.8 S/m, ascribed to perfect 3D CuNWs-TAGA conductive network structures. Meanwhile, the corresponding elasticity modulus, hardness, glass transition temperature (Tg) and heat-resistance index (THRI) of the CuNWs-TAGA/epoxy nanocomposites increase to 4.69 GPa, 0.33 GPa, 126.3 °C and 181.7 °C, respectively.

KW - A. Polymer-matrix composites (PMCs)

KW - B. Thermal properties

KW - C. Electron microscopy

KW - D. Casting

UR - https://www.scopus.com/pages/publications/85073618682

U2 - 10.1016/j.compositesa.2019.105670

DO - 10.1016/j.compositesa.2019.105670

M3 - 文章

AN - SCOPUS:85073618682

SN - 1359-835X

VL - 128

JO - Composites Part A: Applied Science and Manufacturing

JF - Composites Part A: Applied Science and Manufacturing

M1 - 105670

ER -

Synchronously improved electromagnetic interference shielding and thermal conductivity for epoxy nanocomposites by constructing 3D copper nanowires/thermally annealed graphene aerogel framework

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Keywords

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