Abstract
Supramolecular steric hindrance designs make pyrene-functionalized spiro[fluorene-9,7′-dibenzo[c,h]acridine]-5′-one (Py-SFDBAO) assemble into 2D nanostructures that facilitate aqueous phase large-area synthesis of high-quality and uniform crystalline thin films. Thin-film diodes using aqueous nanosheets as active layers exhibit a non-volatile bistable electrical switching feature with ON/OFF ratios of 6.0 × 104 and photoswitching with conductive gains of 102-103. Organic nanosheets are potentially key components for eco-friendly aqueous dispersed organic nano-inks in the application of printed and flexible electronics.
| Original language | English |
|---|---|
| Pages (from-to) | 3664-3669 |
| Number of pages | 6 |
| Journal | Advanced Materials |
| Volume | 25 |
| Issue number | 27 |
| DOIs | |
| State | Published - 19 Jul 2013 |
| Externally published | Yes |
Keywords
- nanocrystals
- organic devices
- self-assembly
- spiro compounds
- thin films
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