Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group

Duo Feng Tang; Gui An Wen; Xiao Ying Qi; Hong Yu Wang; Bo Peng; Wei Wei; Wei Huang

doi:10.1016/j.polymer.2007.05.067

Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group

Duo Feng Tang
, Gui An Wen
, Xiao Ying Qi
, Hong Yu Wang
, Bo Peng
, Wei Wei
, Wei Huang

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Two kinds of blue light-emitting hyperbranched crosslinkable polyfluorene P1 and P2 with different contents of branch unit were synthesized via the palladium-catalyzed Suzuki coupling reaction, and the linear crosslinkable polyfluorene P0 was also prepared for comparison. The molecular weight and thermal behavior of the polymers were measured by GPC, DSC and TGA. Compared with uncrosslinked P0, P1 and P2, the photoluminescence spectra of crosslinked P0, P1 and P2 were little influenced. After annealing for 3 h at 200 °C in air, the photoluminescence spectrum of P2 with higher contents of branch unit showed more excellent stability compared with that of P1 and P0. The spectrum-stable hyperbranched polyfluorene can be used in multilayer and multicolor PLED.

Original language	English
Pages (from-to)	4412-4418
Number of pages	7
Journal	Polymer
Volume	48
Issue number	15
DOIs	https://doi.org/10.1016/j.polymer.2007.05.067
State	Published - 13 Jul 2007
Externally published	Yes

Keywords

Hyperbranched
Photocrosslink
Polyfluorene

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10.1016/j.polymer.2007.05.067

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title = "Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group",

abstract = "Two kinds of blue light-emitting hyperbranched crosslinkable polyfluorene P1 and P2 with different contents of branch unit were synthesized via the palladium-catalyzed Suzuki coupling reaction, and the linear crosslinkable polyfluorene P0 was also prepared for comparison. The molecular weight and thermal behavior of the polymers were measured by GPC, DSC and TGA. Compared with uncrosslinked P0, P1 and P2, the photoluminescence spectra of crosslinked P0, P1 and P2 were little influenced. After annealing for 3 h at 200 °C in air, the photoluminescence spectrum of P2 with higher contents of branch unit showed more excellent stability compared with that of P1 and P0. The spectrum-stable hyperbranched polyfluorene can be used in multilayer and multicolor PLED.",

keywords = "Hyperbranched, Photocrosslink, Polyfluorene",

author = "Tang, \{Duo Feng\} and Wen, \{Gui An\} and Qi, \{Xiao Ying\} and Wang, \{Hong Yu\} and Bo Peng and Wei Wei and Wei Huang",

year = "2007",

month = jul,

day = "13",

doi = "10.1016/j.polymer.2007.05.067",

language = "英语",

volume = "48",

pages = "4412--4418",

journal = "Polymer",

issn = "0032-3861",

publisher = "Elsevier B.V.",

number = "15",

}

TY - JOUR

T1 - Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group

AU - Tang, Duo Feng

AU - Wen, Gui An

AU - Qi, Xiao Ying

AU - Wang, Hong Yu

AU - Peng, Bo

AU - Wei, Wei

AU - Huang, Wei

PY - 2007/7/13

Y1 - 2007/7/13

N2 - Two kinds of blue light-emitting hyperbranched crosslinkable polyfluorene P1 and P2 with different contents of branch unit were synthesized via the palladium-catalyzed Suzuki coupling reaction, and the linear crosslinkable polyfluorene P0 was also prepared for comparison. The molecular weight and thermal behavior of the polymers were measured by GPC, DSC and TGA. Compared with uncrosslinked P0, P1 and P2, the photoluminescence spectra of crosslinked P0, P1 and P2 were little influenced. After annealing for 3 h at 200 °C in air, the photoluminescence spectrum of P2 with higher contents of branch unit showed more excellent stability compared with that of P1 and P0. The spectrum-stable hyperbranched polyfluorene can be used in multilayer and multicolor PLED.

AB - Two kinds of blue light-emitting hyperbranched crosslinkable polyfluorene P1 and P2 with different contents of branch unit were synthesized via the palladium-catalyzed Suzuki coupling reaction, and the linear crosslinkable polyfluorene P0 was also prepared for comparison. The molecular weight and thermal behavior of the polymers were measured by GPC, DSC and TGA. Compared with uncrosslinked P0, P1 and P2, the photoluminescence spectra of crosslinked P0, P1 and P2 were little influenced. After annealing for 3 h at 200 °C in air, the photoluminescence spectrum of P2 with higher contents of branch unit showed more excellent stability compared with that of P1 and P0. The spectrum-stable hyperbranched polyfluorene can be used in multilayer and multicolor PLED.

KW - Hyperbranched

KW - Photocrosslink

KW - Polyfluorene

UR - https://www.scopus.com/pages/publications/34347348087

U2 - 10.1016/j.polymer.2007.05.067

DO - 10.1016/j.polymer.2007.05.067

M3 - 文章

AN - SCOPUS:34347348087

SN - 0032-3861

VL - 48

SP - 4412

EP - 4418

JO - Polymer

JF - Polymer

IS - 15

ER -

Spectrum-stable hyperbranched polyfluorene with photocrosslinkable group

Abstract

Keywords

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