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Some ferrocenyl Schiff bases with nonlinear optical properties

  • Guo Sheng Huang
  • , Yong Min Liang
  • , Xiao Li Wu
  • , Wei Min Liu
  • , Yong Xiang Ma
  • Lanzhou University
  • CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journalArticlepeer-review

35 Scopus citations

Abstract

Eleven new ferrocenyl Schiff bases containing a benzene ring and C=N in a conjugating chain have been synthesized by facile methods and characterized by 1H NMR, elemental analysis and fast atom bombardment mass spectrometry. Cyclic voltammetry was used to determine their electrochemical properties and electron-withdrawing effects. It is shown that these pull-push ferrocenyl compounds have nonlinear optical responses according to their electronic absorption spectra and powder second harmonic generation measurements.

Original languageEnglish
Pages (from-to)706-710
Number of pages5
JournalApplied Organometallic Chemistry
Volume17
Issue number9
DOIs
StatePublished - 1 Sep 2003
Externally publishedYes

Keywords

  • Cyclic voltammetry
  • Electronic absorption spectra
  • Ferrocenyl Schiff base
  • NLO
  • Powder SHG

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