Single-source-precursor derived SiHfBCN enhancing oxidation resistance of SiC/SiC composites in wet oxygen

Xinming Xu; Xingang Luan; Jiahao Zhang; Xinxin Cao; Laifei Cheng; Ralf Riedel

doi:10.1016/j.corsci.2022.110602

Single-source-precursor derived SiHfBCN enhancing oxidation resistance of SiC/SiC composites in wet oxygen

Xinming Xu
, Xingang Luan
, Jiahao Zhang
, Xinxin Cao
, Laifei Cheng
, Ralf Riedel

School of Materials Sience and Engineering

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Semi-dense SiC fiber reinforced SiC (SiC/SiC) composites were modified by single-source-precursor derived SiHfBCN ceramics to obtain SiC/SiC-SiHfBCN composites with enhanced wet oxidation resistance. Wet oxidation behavior of SiC/SiC-SiHfBCN composites at 1200–1400 ℃ in different atmospheres were investigated. It was found that the SiC-SiHfBCN ceramic matrix can provide at least 100 h of damage-free protection for SiC fibers up to 1300 ℃ in wet oxygen. HfSiO₄ with low oxygen diffusivity is found on the surface of SiC/SiC-SiHfBCN composites after oxidation, which is discussed in terms of diffusion of HfO₂ from the bulk to the surface via liquids.

Original language	English
Article number	110602
Journal	Corrosion Science
Volume	208
DOIs	https://doi.org/10.1016/j.corsci.2022.110602
State	Published - Nov 2022

Keywords

Self-healing
SiC/SiC
SiHfBCN
Wet oxidation resistance

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10.1016/j.corsci.2022.110602

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@article{e008436d3cb4434f9e7477c1a5ef667e,

title = "Single-source-precursor derived SiHfBCN enhancing oxidation resistance of SiC/SiC composites in wet oxygen",

abstract = "Semi-dense SiC fiber reinforced SiC (SiC/SiC) composites were modified by single-source-precursor derived SiHfBCN ceramics to obtain SiC/SiC-SiHfBCN composites with enhanced wet oxidation resistance. Wet oxidation behavior of SiC/SiC-SiHfBCN composites at 1200–1400 ℃ in different atmospheres were investigated. It was found that the SiC-SiHfBCN ceramic matrix can provide at least 100 h of damage-free protection for SiC fibers up to 1300 ℃ in wet oxygen. HfSiO4 with low oxygen diffusivity is found on the surface of SiC/SiC-SiHfBCN composites after oxidation, which is discussed in terms of diffusion of HfO2 from the bulk to the surface via liquids.",

keywords = "Self-healing, SiC/SiC, SiHfBCN, Wet oxidation resistance",

author = "Xinming Xu and Xingang Luan and Jiahao Zhang and Xinxin Cao and Laifei Cheng and Ralf Riedel",

note = "Publisher Copyright: {\textcopyright} 2022 Elsevier Ltd",

year = "2022",

month = nov,

doi = "10.1016/j.corsci.2022.110602",

language = "英语",

volume = "208",

journal = "Corrosion Science",

issn = "0010-938X",

publisher = "Elsevier Ltd",

}

TY - JOUR

T1 - Single-source-precursor derived SiHfBCN enhancing oxidation resistance of SiC/SiC composites in wet oxygen

AU - Xu, Xinming

AU - Luan, Xingang

AU - Zhang, Jiahao

AU - Cao, Xinxin

AU - Cheng, Laifei

AU - Riedel, Ralf

PY - 2022/11

Y1 - 2022/11

N2 - Semi-dense SiC fiber reinforced SiC (SiC/SiC) composites were modified by single-source-precursor derived SiHfBCN ceramics to obtain SiC/SiC-SiHfBCN composites with enhanced wet oxidation resistance. Wet oxidation behavior of SiC/SiC-SiHfBCN composites at 1200–1400 ℃ in different atmospheres were investigated. It was found that the SiC-SiHfBCN ceramic matrix can provide at least 100 h of damage-free protection for SiC fibers up to 1300 ℃ in wet oxygen. HfSiO4 with low oxygen diffusivity is found on the surface of SiC/SiC-SiHfBCN composites after oxidation, which is discussed in terms of diffusion of HfO2 from the bulk to the surface via liquids.

AB - Semi-dense SiC fiber reinforced SiC (SiC/SiC) composites were modified by single-source-precursor derived SiHfBCN ceramics to obtain SiC/SiC-SiHfBCN composites with enhanced wet oxidation resistance. Wet oxidation behavior of SiC/SiC-SiHfBCN composites at 1200–1400 ℃ in different atmospheres were investigated. It was found that the SiC-SiHfBCN ceramic matrix can provide at least 100 h of damage-free protection for SiC fibers up to 1300 ℃ in wet oxygen. HfSiO4 with low oxygen diffusivity is found on the surface of SiC/SiC-SiHfBCN composites after oxidation, which is discussed in terms of diffusion of HfO2 from the bulk to the surface via liquids.

KW - Self-healing

KW - SiC/SiC

KW - SiHfBCN

KW - Wet oxidation resistance

UR - https://www.scopus.com/pages/publications/85137057427

U2 - 10.1016/j.corsci.2022.110602

DO - 10.1016/j.corsci.2022.110602

M3 - 文章

AN - SCOPUS:85137057427

SN - 0010-938X

VL - 208

JO - Corrosion Science

JF - Corrosion Science

M1 - 110602

ER -

Single-source-precursor derived SiHfBCN enhancing oxidation resistance of SiC/SiC composites in wet oxygen

Abstract

Keywords

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