Self-assembly of ionic liquids and metal complexes in super-cages of NaY. Integration of free catalysts and solvent molecules into confined catalytic sites

Yubo Ma; Yude He; Qinghua Zhang; Feng Shi; Xiangyuan Ma; Liujin Lu; Youquan Deng

doi:10.1016/s1872-2067(09)60090-5

Self-assembly of ionic liquids and metal complexes in super-cages of NaY. Integration of free catalysts and solvent molecules into confined catalytic sites

Yubo Ma
, Yude He
, Qinghua Zhang
, Feng Shi
, Xiangyuan Ma
, Liujin Lu
, Youquan Deng

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

The integration of a free metal complex, Pd(phen)²⁺, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3000 to 23000 h^-1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl₂/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis.

Original language	English
Pages (from-to)	933-937
Number of pages	5
Journal	Chinese Journal of Catalysis
Volume	31
Issue number	8
DOIs	https://doi.org/10.1016/s1872-2067(09)60090-5
State	Published - Aug 2010
Externally published	Yes

Keywords

Active site
Aniline
Carbonylation
Ionic liquid
Metal complex
Phenyl methyl carbamate
Turn over frequency

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10.1016/s1872-2067(09)60090-5

Cite this

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title = "Self-assembly of ionic liquids and metal complexes in super-cages of NaY. Integration of free catalysts and solvent molecules into confined catalytic sites",

abstract = "The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3000 to 23000 h-1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis.",

keywords = "Active site, Aniline, Carbonylation, Ionic liquid, Metal complex, Phenyl methyl carbamate, Turn over frequency",

author = "Yubo Ma and Yude He and Qinghua Zhang and Feng Shi and Xiangyuan Ma and Liujin Lu and Youquan Deng",

year = "2010",

month = aug,

doi = "10.1016/s1872-2067(09)60090-5",

language = "英语",

volume = "31",

pages = "933--937",

journal = "Chinese Journal of Catalysis",

issn = "1872-2067",

publisher = "Science Press ",

number = "8",

}

TY - JOUR

T1 - Self-assembly of ionic liquids and metal complexes in super-cages of NaY. Integration of free catalysts and solvent molecules into confined catalytic sites

AU - Ma, Yubo

AU - He, Yude

AU - Zhang, Qinghua

AU - Shi, Feng

AU - Ma, Xiangyuan

AU - Lu, Liujin

AU - Deng, Youquan

PY - 2010/8

Y1 - 2010/8

N2 - The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3000 to 23000 h-1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis.

AB - The integration of a free metal complex, Pd(phen)2+, and a room temperature ionic liquid (IL) solvent molecule, 1-decyl-3-methyl imidazolium bromide, into a complete catalytically active site and confined in a NaY zeolite super-cage with an appropriate spatial arrangement was investigated. This integration was achieved through a molecular self-assembly method. A preliminary test of this catalyst system for the carbonylation of aniline to methyl phenyl carbamate indicated that far higher catalytic activity could be achieved (TOF increased from 3000 to 23000 h-1) with far lower amounts of the IL solvent and the Pd complex in comparison with a simple mixture of Pd(phen)Cl2/IL/NaY as the catalyst. This new system can also be applied to other areas of catalysis.

KW - Active site

KW - Aniline

KW - Carbonylation

KW - Ionic liquid

KW - Metal complex

KW - Phenyl methyl carbamate

KW - Turn over frequency

UR - https://www.scopus.com/pages/publications/77956501286

U2 - 10.1016/s1872-2067(09)60090-5

DO - 10.1016/s1872-2067(09)60090-5

M3 - 文章

AN - SCOPUS:77956501286

SN - 1872-2067

VL - 31

SP - 933

EP - 937

JO - Chinese Journal of Catalysis

JF - Chinese Journal of Catalysis

IS - 8

ER -

Self-assembly of ionic liquids and metal complexes in super-cages of NaY. Integration of free catalysts and solvent molecules into confined catalytic sites

Abstract

Keywords

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