Sapphire optical fiber with (BN/SiBCN)_n coating prepared by chemical vapor deposition for high-temperature sensing applications

To enhance the load-bearing capacity of sapphire optical fiber (SOF) in extreme environments, this study prepared SOF/(BN/SiBCN)_n by optimizing the nanostructure through increased deposition temperature of BN using alternating chemical vapor deposition. Simulation results indicated an inverse correlation between the leakage loss of SOF/BN/SiBCN and BN thickness; at room temperature, the tendency for coating cracking along the radial direction of SOF/BN/SiBCN is positively correlated with BN thickness, whereas this trend reverses at 1500 °C. Mechanical testing revealed that the tensile strength of SOF/BN/SiBCN is inversely correlated with the tendency for interlayer cracking, aligning with the findings from residual stress simulations; under an air environment at 1500 °C, SOF/(BN/SiBCN)₂ exhibited the highest tensile strength, indicating that the layered matrix design effectively mitigates the risk of BN oxidation by creating barrier layers. Optical test demonstrated that the BN coating functions as a total reflection layer to suppress the scattering of optical signals on the sapphire optical fiber surface. In conclusion, the coating design of SOF/(BN/SiBCN)_n could meet the material requirements for sapphire optical fiber sensors in extreme environments.