Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds

Chao Yan; Xiujuan Qi; Kangcai Wang; Yunhe Jin; Guangbin Cheng; Tianlin Liu; Hongwei Yang; Qinghua Zhang

doi:10.1039/C8CC10178G

Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds

Chao Yan
, Xiujuan Qi
, Kangcai Wang
, Yunhe Jin
, Guangbin Cheng
, Tianlin Liu
, Hongwei Yang
, Qinghua Zhang

China Academy of Engineering Physics
Southwest University of Science and Technology
Nanjing University of Science and Technology

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.

Original language	English
Pages (from-to)	3497-3500
Number of pages	4
Journal	Chemical Communications
Volume	55
Issue number	24
DOIs	https://doi.org/10.1039/C8CC10178G
State	Published - 2019
Externally published	Yes

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title = "Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds",

abstract = "A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.",

author = "Chao Yan and Xiujuan Qi and Kangcai Wang and Yunhe Jin and Guangbin Cheng and Tianlin Liu and Hongwei Yang and Qinghua Zhang",

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doi = "10.1039/C8CC10178G",

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journal = "Chemical Communications",

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T2 - cyclization of FOX-7 affords the fused-ring polynitro compounds

AU - Yan, Chao

AU - Qi, Xiujuan

AU - Wang, Kangcai

AU - Jin, Yunhe

AU - Cheng, Guangbin

AU - Liu, Tianlin

AU - Yang, Hongwei

AU - Zhang, Qinghua

PY - 2019

Y1 - 2019

N2 - A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.

AB - A novel fused-ring polynitro compound (5) and a cyclic compound featuring gem-dinitromethylene and nitroso groups (7) were synthesized from 1,1-diamino-2,2-dinitroethylene (FOX-7). Both compounds exhibit high density, decent thermal stability, high detonation performances, and low mechanical sensitivities. This newly developed derivatization strategy enriches the ever-expanding reactive chemistry of FOX-7.

UR - https://www.scopus.com/pages/publications/85063111291

U2 - 10.1039/C8CC10178G

DO - 10.1039/C8CC10178G

M3 - 文章

C2 - 30834905

AN - SCOPUS:85063111291

SN - 1359-7345

VL - 55

SP - 3497

EP - 3500

JO - Chemical Communications

JF - Chemical Communications

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ER -

Revisiting the reactive chemistry of FOX-7: cyclization of FOX-7 affords the fused-ring polynitro compounds

Abstract

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