Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Zhijie Chen; Penghao Li; Xuan Zhang; Peng Li; Megan C. Wasson; Timur Islamoglu; J. Fraser Stoddart; Omar K. Farha

doi:10.1021/jacs.8b13710

Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Zhijie Chen
, Penghao Li
, Xuan Zhang
, Peng Li
, Megan C. Wasson
, Timur Islamoglu
, J. Fraser Stoddart
, Omar K. Farha

Northwestern University
Fudan University
Tianjin University
University of New South Wales

Research output: Contribution to journal › Article › peer-review

219 Scopus citations

Abstract

Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe ³⁺ , Cr ³⁺ , and Sc ³⁺ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

Original language	English
Pages (from-to)	2900-2905
Number of pages	6
Journal	Journal of the American Chemical Society
Volume	141
Issue number	7
DOIs	https://doi.org/10.1021/jacs.8b13710
State	Published - 20 Feb 2019
Externally published	Yes

Access to Document

10.1021/jacs.8b13710

Cite this

@article{ac961426cf784542b5bb6ba6ffa3d3e3,

title = "Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption",

abstract = " Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.",

author = "Zhijie Chen and Penghao Li and Xuan Zhang and Peng Li and Wasson, \{Megan C.\} and Timur Islamoglu and Stoddart, \{J. Fraser\} and Farha, \{Omar K.\}",

note = "Publisher Copyright: {\textcopyright} 2019 American Chemical Society.",

year = "2019",

month = feb,

day = "20",

doi = "10.1021/jacs.8b13710",

language = "英语",

volume = "141",

pages = "2900--2905",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "7",

}

TY - JOUR

T1 - Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

AU - Chen, Zhijie

AU - Li, Penghao

AU - Zhang, Xuan

AU - Li, Peng

AU - Wasson, Megan C.

AU - Islamoglu, Timur

AU - Stoddart, J. Fraser

AU - Farha, Omar K.

PY - 2019/2/20

Y1 - 2019/2/20

N2 - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

AB - Metal-organic frameworks (MOFs) based on edge-transitive 6-c acs nets are well-developed and can be synthesized from trinuclear metal clusters and ditopic ligands, i.e., MOF-235 and MIL-88. The rational design of noncatenated acs-MOFs by symmetry-matching between trigonal prismatic organic ligands and trinuclear clusters, however, remains a great challenge. Herein, we report a series of acs-MOFs (NU-1500) based on trivalent trinuclear metal (Fe 3+ , Cr 3+ , and Sc 3+ ) clusters and a rigid trigonal prismatic ligand courtesy of reticular chemistry. The highly porous and hydrolytically stable NU-1500-Cr can be activated directly from water and displays an impressive water vapor uptake with small hysteresis.

UR - https://www.scopus.com/pages/publications/85061537747

U2 - 10.1021/jacs.8b13710

DO - 10.1021/jacs.8b13710

M3 - 文章

C2 - 30735359

AN - SCOPUS:85061537747

SN - 0002-7863

VL - 141

SP - 2900

EP - 2905

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 7

ER -

Reticular Access to Highly Porous acs-MOFs with Rigid Trigonal Prismatic Linkers for Water Sorption

Abstract

Access to Document

Other files and links

Fingerprint

Cite this