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Redox-responsive organometallic microgel particles prepared from poly(ferrocenylsilane)s generated using microfluidics

  • Xiaofeng Sui
  • , Lingling Shui
  • , Jin Cui
  • , Yanbo Xie
  • , Jing Song
  • , Albert Van Den Berg
  • , Mark A. Hempenius
  • , G. Julius Vancso
  • University of Twente
  • South China Normal University
  • Agency for Science, Technology and Research, Singapore

Research output: Contribution to journalArticlepeer-review

29 Scopus citations

Abstract

We describe a novel and versatile method for the fabrication of poly(ferrocenylsilane) (PFS) based microspheres using microfluidics. Cross-linked microgel particles were obtained by UV-induced crosslinking of precursor droplets. By variations in the substitution of the silane units of PFS, organogel as well as hydrogel particles were prepared. Applications of these redox active microspheres to form in situ Ag nanoparticles, as well as loading and release of guest molecules were demonstrated.

Original languageEnglish
Pages (from-to)3058-3060
Number of pages3
JournalChemical Communications
Volume50
Issue number23
DOIs
StatePublished - 20 Feb 2014
Externally publishedYes

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