Properties of E-51/DDS epoxy resin toughened by alkaline EPb-POSS

Ling Xia Wang; Xiao Yan Ma; Long Jin; Fang Chen; Tao Wu

doi:10.11868/j.issn.1001-4381.2016.11.005

Properties of E-51/DDS epoxy resin toughened by alkaline EP_b-POSS

Ling Xia Wang
, Xiao Yan Ma
, Long Jin
, Fang Chen
, Tao Wu

School of Chemistry and Chemical Engineering

Northwestern Polytechnical University Xian

Research output: Contribution to journal › Article › peer-review

4 Scopus citations

Abstract

The bisphenol A epoxy resin (E-51) / 4,4'- diaminodiphenyl sulfone (DDS) was modified by the epoxy silsesquioxane (EP_b-POSS), which was synthesized by hydrolytic condensation of (γ-glycidoxypropyl)trimethoxysilane under basic condition, to prepare EP_b-POSS/E-51/DDS modified resin systems. The curing process and the influence of EP_b-POSS with different contents on the mechanical properties and thermal stability of the modified resin systems was studied. The results show that although the EP_b-POSS have little effect on the curing process and the stiffness of the modified resin, it can significantly improve the toughness; when the mass fraction of EP_b-POSS is 1.0%, the impact strength of the modified resin can reach 49.2kJ·m², is increased by 90.0%, and shows obvious toughness fracture; the bending strength is 132.8MPa, is slightly increased; and the initial decomposition temperature is 378.0℃, is increased by 26.0℃.

Original language	English
Pages (from-to)	33-38
Number of pages	6
Journal	Cailiao Gongcheng/Journal of Materials Engineering
Volume	44
Issue number	11
DOIs	https://doi.org/10.11868/j.issn.1001-4381.2016.11.005
State	Published - 20 Nov 2016

Keywords

Epoxy resin
Silsesquioxane
Thermal stability
Toughness

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10.11868/j.issn.1001-4381.2016.11.005

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title = "Properties of E-51/DDS epoxy resin toughened by alkaline EPb-POSS",

abstract = "The bisphenol A epoxy resin (E-51) / 4,4'- diaminodiphenyl sulfone (DDS) was modified by the epoxy silsesquioxane (EPb-POSS), which was synthesized by hydrolytic condensation of (γ-glycidoxypropyl)trimethoxysilane under basic condition, to prepare EPb-POSS/E-51/DDS modified resin systems. The curing process and the influence of EPb-POSS with different contents on the mechanical properties and thermal stability of the modified resin systems was studied. The results show that although the EPb-POSS have little effect on the curing process and the stiffness of the modified resin, it can significantly improve the toughness; when the mass fraction of EPb-POSS is 1.0\%, the impact strength of the modified resin can reach 49.2kJ·m2, is increased by 90.0\%, and shows obvious toughness fracture; the bending strength is 132.8MPa, is slightly increased; and the initial decomposition temperature is 378.0℃, is increased by 26.0℃.",

keywords = "Epoxy resin, Silsesquioxane, Thermal stability, Toughness",

author = "Wang, \{Ling Xia\} and Ma, \{Xiao Yan\} and Long Jin and Fang Chen and Tao Wu",

year = "2016",

month = nov,

day = "20",

doi = "10.11868/j.issn.1001-4381.2016.11.005",

language = "英语",

volume = "44",

pages = "33--38",

journal = "Cailiao Gongcheng/Journal of Materials Engineering",

issn = "1001-4381",

publisher = "Science Press ",

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TY - JOUR

T1 - Properties of E-51/DDS epoxy resin toughened by alkaline EPb-POSS

AU - Wang, Ling Xia

AU - Ma, Xiao Yan

AU - Jin, Long

AU - Chen, Fang

AU - Wu, Tao

PY - 2016/11/20

Y1 - 2016/11/20

N2 - The bisphenol A epoxy resin (E-51) / 4,4'- diaminodiphenyl sulfone (DDS) was modified by the epoxy silsesquioxane (EPb-POSS), which was synthesized by hydrolytic condensation of (γ-glycidoxypropyl)trimethoxysilane under basic condition, to prepare EPb-POSS/E-51/DDS modified resin systems. The curing process and the influence of EPb-POSS with different contents on the mechanical properties and thermal stability of the modified resin systems was studied. The results show that although the EPb-POSS have little effect on the curing process and the stiffness of the modified resin, it can significantly improve the toughness; when the mass fraction of EPb-POSS is 1.0%, the impact strength of the modified resin can reach 49.2kJ·m2, is increased by 90.0%, and shows obvious toughness fracture; the bending strength is 132.8MPa, is slightly increased; and the initial decomposition temperature is 378.0℃, is increased by 26.0℃.

AB - The bisphenol A epoxy resin (E-51) / 4,4'- diaminodiphenyl sulfone (DDS) was modified by the epoxy silsesquioxane (EPb-POSS), which was synthesized by hydrolytic condensation of (γ-glycidoxypropyl)trimethoxysilane under basic condition, to prepare EPb-POSS/E-51/DDS modified resin systems. The curing process and the influence of EPb-POSS with different contents on the mechanical properties and thermal stability of the modified resin systems was studied. The results show that although the EPb-POSS have little effect on the curing process and the stiffness of the modified resin, it can significantly improve the toughness; when the mass fraction of EPb-POSS is 1.0%, the impact strength of the modified resin can reach 49.2kJ·m2, is increased by 90.0%, and shows obvious toughness fracture; the bending strength is 132.8MPa, is slightly increased; and the initial decomposition temperature is 378.0℃, is increased by 26.0℃.

KW - Epoxy resin

KW - Silsesquioxane

KW - Thermal stability

KW - Toughness

UR - https://www.scopus.com/pages/publications/84999232912

U2 - 10.11868/j.issn.1001-4381.2016.11.005

DO - 10.11868/j.issn.1001-4381.2016.11.005

M3 - 文章

AN - SCOPUS:84999232912

SN - 1001-4381

VL - 44

SP - 33

EP - 38

JO - Cailiao Gongcheng/Journal of Materials Engineering

JF - Cailiao Gongcheng/Journal of Materials Engineering

IS - 11

ER -

Properties of E-51/DDS epoxy resin toughened by alkaline EP_b-POSS

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Keywords

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