Preparation of ferrocenyl mono- and dienone derivatives through aldol condensation of 1,1′-diacetylferrocene with aromatic aldehydes in dry conditions

Wan yi Liu; Qi hai Xu; Bao hua Chen; Yong min Liang; Yong xiang Ma; Wei min Liu

doi:10.1016/S0022-328X(01)00927-5

Preparation of ferrocenyl mono- and dienone derivatives through aldol condensation of 1,1′-diacetylferrocene with aromatic aldehydes in dry conditions

Wan yi Liu
, Qi hai Xu
, Bao hua Chen
, Yong min Liang
, Yong xiang Ma
, Wei min Liu

Lanzhou University
CAS - Lanzhou Institute of Chemical Physics

Research output: Contribution to journal › Article › peer-review

14 Scopus citations

Abstract

1,1′-Diacetylferrocene was condensed with aromatic aldehydes without solvent in the presence of solid NaOH. Diacetylferrocene can give good yields of mono- or diene with either one or two molecules of a wide range of aldehydes depending only on the stoichiometry. Cyclization to ferrocenphane does not occur in this condition.

Original language	English
Pages (from-to)	782-785
Number of pages	4
Journal	Journal of Organometallic Chemistry
Volume	637-639
DOIs	https://doi.org/10.1016/S0022-328X(01)00927-5
State	Published - 3 Dec 2001
Externally published	Yes

Keywords

1,1′-Diacetylferrocene
1,1′-Dienonylferrocenes
1-Acetyl-1′-enonylferrocenes
Aldol condensation
Solid-state reaction

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10.1016/S0022-328X(01)00927-5

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@article{04f30bb6b7954023afbfa2afa799cbfb,

title = "Preparation of ferrocenyl mono- and dienone derivatives through aldol condensation of 1,1′-diacetylferrocene with aromatic aldehydes in dry conditions",

abstract = "1,1′-Diacetylferrocene was condensed with aromatic aldehydes without solvent in the presence of solid NaOH. Diacetylferrocene can give good yields of mono- or diene with either one or two molecules of a wide range of aldehydes depending only on the stoichiometry. Cyclization to ferrocenphane does not occur in this condition.",

keywords = "1,1′-Diacetylferrocene, 1,1′-Dienonylferrocenes, 1-Acetyl-1′-enonylferrocenes, Aldol condensation, Solid-state reaction",

author = "Liu, \{Wan yi\} and Xu, \{Qi hai\} and Chen, \{Bao hua\} and Liang, \{Yong min\} and Ma, \{Yong xiang\} and Liu, \{Wei min\}",

year = "2001",

month = dec,

day = "3",

doi = "10.1016/S0022-328X(01)00927-5",

language = "英语",

volume = "637-639",

pages = "782--785",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

}

TY - JOUR

T1 - Preparation of ferrocenyl mono- and dienone derivatives through aldol condensation of 1,1′-diacetylferrocene with aromatic aldehydes in dry conditions

AU - Liu, Wan yi

AU - Xu, Qi hai

AU - Chen, Bao hua

AU - Liang, Yong min

AU - Ma, Yong xiang

AU - Liu, Wei min

PY - 2001/12/3

Y1 - 2001/12/3

N2 - 1,1′-Diacetylferrocene was condensed with aromatic aldehydes without solvent in the presence of solid NaOH. Diacetylferrocene can give good yields of mono- or diene with either one or two molecules of a wide range of aldehydes depending only on the stoichiometry. Cyclization to ferrocenphane does not occur in this condition.

AB - 1,1′-Diacetylferrocene was condensed with aromatic aldehydes without solvent in the presence of solid NaOH. Diacetylferrocene can give good yields of mono- or diene with either one or two molecules of a wide range of aldehydes depending only on the stoichiometry. Cyclization to ferrocenphane does not occur in this condition.

KW - 1,1′-Diacetylferrocene

KW - 1,1′-Dienonylferrocenes

KW - 1-Acetyl-1′-enonylferrocenes

KW - Aldol condensation

KW - Solid-state reaction

UR - https://www.scopus.com/pages/publications/18244429864

U2 - 10.1016/S0022-328X(01)00927-5

DO - 10.1016/S0022-328X(01)00927-5

M3 - 文章

AN - SCOPUS:18244429864

SN - 0022-328X

VL - 637-639

SP - 782

EP - 785

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

ER -

Preparation of ferrocenyl mono- and dienone derivatives through aldol condensation of 1,1′-diacetylferrocene with aromatic aldehydes in dry conditions

Abstract

Keywords

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